138002-59-2Relevant academic research and scientific papers
Dimethoxy aromatic compounds VIII. Degenerate dealkylation-realkylation reaction of 1-bis(2,4-dimethoxyphenyl)-2-methylpropane
Natoli,Ceraulo,Lamartina,Ferrugia
, p. 375 - 376 (1994)
The condensation reaction under acid condition of the benzylic alcohols 1, 2 and 3 with the hexadeutero dimethoxybenzenes 4, 5 and 6 leads to the expected hexadeutero bis(dimethoxyphenyl)-2-methylpropanes 7, 8 and 9, respectively. However, the presence of both dodecadeutero and unlabelled 1- bis(2,4-dimethoxyphenyl)-2-methylpropanes 10 and 11 indicates that 9 undergoes a rapid degenerate dealkylation-alkylation reaction.
Hydrogen-Carbon, Carbon-Carbon Double Rearrangement Induced by Proximity Effects
Ceraulo, Leopoldo,Natoli, Maria Concetta,Agozzino, Pasquale,Ferrugia, Mirella,Lamartina, Liliana
, p. 857 - 861 (2007/10/02)
The 75 eV electron impact mass spectra of 1,1-(bis(dimethoxyphenyl)methanes bearing o-methoxy groups are dominated by intense peaks corresponding, at least formally, to benzyl ions + (b).They arise from ions s
