13820-94-5Relevant academic research and scientific papers
Investigations using fluorescent ligands to monitor platinum(iv) reduction and platinum(ii) reactions in cancer cells
New, Elizabeth J.,Duan, Ran,Zhang, Jenny Z.,Hambley, Trevor W.
, p. 3092 - 3101 (2009/08/08)
Coordination of the aniline containing fluorophores, coumarin 120 (C120) and coumarin 151 (C151) at the non-leaving group positions of cisplatin analogues (giving cis-[PtCl2(C120)(NH3)] and cis-[PtCl2(C151)(NH3)
Conversion of Magnus salt into diamminedichloroplatinum(II) isomers in aqueous solution
Starkov,Kozhukhovskaya
, p. 1426 - 1429 (2009/05/06)
The conditions inducing conversion of Magnus salt into diamminedichloroplatinum(II) isomers were studied. Syntheses of cis-diamminedichloroplatinum(II) and trans-diamminedichloroplatinum(II), which are used to prepare potassium or ammonium amminetrichloroplatinate(II), are described. The identity and structure of diamminedichloroplatinum(II) isomers were verified by elemental analysis, X-ray powder diffraction, and IR and UV spectroscopy. A workflow for preparing potassium or ammonium amminetrichloroplatinate(II) from diamminedichloroplatinum(II) isomers was developed. This workflow appreciably increases the product yield due to the return of unused Magnus salt to the main synthesis flow.
