138336-94-4

Usage

General Description

2,2'-Bipyridine, 6,6''-(1,3-phenylene)bis- is a chemical compound with the molecular formula C22H14N2. It is a derivative of 2,2'-bipyridine, and the 1,3-phenylene group is linked to the 6 position of each bipyridine unit. 2,2'-Bipyridine, 6,6''-(1,3-phenylene)bis- is commonly used as a ligand in coordination chemistry, where it can form stable complexes with metal ions. It is also employed in organic synthesis and catalysis reactions due to its ability to facilitate various chemical transformations. Additionally, 2,2'-Bipyridine, 6,6''-(1,3-phenylene)bis- has been investigated for its potential applications in materials science, such as in the development of functional polymers and advanced materials.

Upstream product

• 26482-00-8 1-(2-oxo-2-(2-pyridyl)ethyl)pyridinium iodide 
• 6781-42-6 1,3-diacetylbenzene 
• 1122-62-9 2-acetylpyridine 
• 78570-34-0 3,3-bis(methylsulfanyl)-1-pyridin-2-ylprop-2-en-1-one 
• 138336-93-3 1,3-bis-(4-methylthio-2,2'-bipyridin-6-yl)benzene 

Relevant academic research and scientific papers

Dinuclear Double Helicates incorporating a 1,3-Phenylene Spacer; the Crystal and Molecular Structure of Diacetato-1κ2O-,2κ2O-bis2N,N':2κ2N'',N'''>dinickel Bis(hexafluorophosphate)

Linking two bipyridine units by a 1,3-phenylene spacer has provided a novel class of ligand which promotes the spontaneous self-assembly of double helicates upon reaction with transition-metal ions.Interaction with copper(I) or silver(I) resulted in dinuclear double-helical complexes with the metal ions occupying pseudo-tetrahedral co-ordination sites.Reaction with cobalt(II) or nickel(II) acetates gave similar dinuclear double-helical structures with a didentate acetate ligand completing the co-ordination sphere of each metal to give a pseudo-octahedral geometry.The crystal structure of 22(O2CMe)2>2 2 = 1,3-bis(4-meth ylthio-2,2'-bipyridin-6-yl)benzene> has been determined.The two metal centres are separated by 5.875 Angstroem.In contrast to the helicates formed by the linear oligopyridines, no significant ?-stacking interactions are observed between pyridine moieties on the helical strands.