1383658-46-5

Basic information

• Product Name: C₁₄H₁₃FN₂O₃
• Synonyms: C₁₄H₁₃FN₂O₃
• CAS NO: 1383658-46-5
• Molecular Weight: 276.267
• Mol File: 1383658-46-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₄H₁₃FN₂O₃(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₄H₁₃FN₂O₃(1383658-46-5)
• EPA Substance Registry System: C₁₄H₁₃FN₂O₃(1383658-46-5)

Safety Data

• Hazardous Substances Data: 1383658-46-5(Hazardous Substances Data)

Upstream product

• 130995-12-9 1-(4-fluorophenyl)-2-trimethylsilylacetylene 
• 352-34-1 4-fluoro-1-iodobenzene 
• 766-98-3 1-ethynyl-4-fluorobenzene 
• 623-73-4 diazoacetic acid ethyl ester 
• 1383658-29-4 3-(4-fluorophenyl)cyclobut-2-en-1-one 

Relevant articles and documents

Efficient approach to 1,2-diazepines via formal diazomethylene insertion into the C-C bond of cyclobutenones

Efficient monocyclic 1,2-diazepine formation via a tandem electrocyclization reaction of cyclobutenones with lithiodiazoacetate is demonstrated. The reaction proceeds through an oxy anion-accelerated 4π-ring opening of cyclobutene followed by an 8π-ring closure of the resultant oxy anion-substituted diazo-diene under mild conditions to furnish a 1,2-diazepine via formal diazomethylene insertion into the C-C bond of cyclobutenone.