138381-85-8

Upstream product

• 501-53-1 benzyl chloroformate 
• 19130-96-2 1,5-dideoxy-1,5-imino-D-glucitol 
• 130539-12-7 N-Benzyloxycarbonyl-1,5-dideoxy-1,5-imino-D-glucitol 
• 98-88-4 benzoyl chloride 
• 138381-83-6 4,6-O-(R-Benzylidene)-N-benzyloxycarbonyl-1,5-dideoxy-1,5-imino-D-glucitol 

Downstream Products

• 154865-79-9 (2R,4aR,7S,8R,8aR)-7-Benzoyloxy-8-methoxy-2-phenyl-hexahydro-[1,3]dioxino[5,4-b]pyridine-5-carboxylic acid benzyl ester 
• 154865-76-6 (2R,4aR,7S,8R,8aR)-7-Benzoyloxy-8-(2-methoxy-ethoxymethoxy)-2-phenyl-hexahydro-[1,3]dioxino[5,4-b]pyridine-5-carboxylic acid benzyl ester 
• 154865-78-8 (2R,4aR,7S,8R,8aR)-7-Benzoyloxy-8-(tert-butyl-dimethyl-silanyloxy)-2-phenyl-hexahydro-[1,3]dioxino[5,4-b]pyridine-5-carboxylic acid benzyl ester 
• 154865-77-7 (2R,4aR,7S,8R,8aR)-7-Benzoyloxy-2-phenyl-8-(2-trimethylsilanyl-ethoxymethoxy)-hexahydro-[1,3]dioxino[5,4-b]pyridine-5-carboxylic acid benzyl ester 
• 154865-89-1 (2R,4aR,7S,8S,8aR)-7-Hydroxy-7-methyl-2-phenyl-8-(2-trimethylsilanyl-ethoxymethoxy)-hexahydro-[1,3]dioxino[5,4-b]pyridine-5-carboxylic acid benzyl ester 
• 154865-88-0 (2R,4aR,7R,8S,8aR)-8-(tert-Butyl-dimethyl-silanyloxy)-7-hydroxy-2-phenyl-7-trimethylsilanylmethyl-hexahydro-[1,3]dioxino[5,4-b]pyridine-5-carboxylic acid benzyl ester 
• 154968-03-3 C₂₈H₃₇NO₆Si 
• 154865-85-7 (2R,4aR,8S,8aR)-7-Oxo-2-phenyl-8-(2-trimethylsilanyl-ethoxymethoxy)-hexahydro-[1,3]dioxino[5,4-b]pyridine-5-carboxylic acid benzyl ester 
• 154865-84-6 (2R,4aR,8S,8aR)-8-(2-Methoxy-ethoxymethoxy)-7-oxo-2-phenyl-hexahydro-[1,3]dioxino[5,4-b]pyridine-5-carboxylic acid benzyl ester 
• 154865-81-3 (2R,4aR,7S,8R,8aR)-7-Hydroxy-2-phenyl-8-(2-trimethylsilanyl-ethoxymethoxy)-hexahydro-[1,3]dioxino[5,4-b]pyridine-5-carboxylic acid benzyl ester 
• 154865-80-2 (2R,4aR,7S,8R,8aR)-7-Hydroxy-8-(2-methoxy-ethoxymethoxy)-2-phenyl-hexahydro-[1,3]dioxino[5,4-b]pyridine-5-carboxylic acid benzyl ester 
• 154865-86-8 (2R,4aR,8S,8aR)-8-(tert-Butyl-dimethyl-silanyloxy)-7-oxo-2-phenyl-hexahydro-[1,3]dioxino[5,4-b]pyridine-5-carboxylic acid benzyl ester 
• 154866-07-6 (2R,4aR,8R,8aR)-8-(tert-Butyl-dimethyl-silanyloxy)-7-methylene-2-phenyl-hexahydro-[1,3]dioxino[5,4-b]pyridine-5-carboxylic acid benzyl ester 

Relevant academic research and scientific papers

The synthesis of 1,5-dideoxy-1,5-(alkyl)imino-2-C-methyl-D-glucitols

The regio- and stereoselective synthesis of the title compounds 3 and 4 has been accomplished starting with deoxynojirimycin. The factors affecting the stereochemical outcome of Grignard addition to the key carbonyl intermediate are discussed.

2-substituted tertiary carbinol derivatives of deoxynojirimycin

2-Substituted tertiary carbinol derivatives of deoxynojirimycin are disclosed having the formula STR1 wherein R4 =an alkyl, vinyl, alkenyl, alkynyl, aryl, aralkyl, alkenylalkyl, alkylnylalkyl or CH2 Y substituent having from about 1