138524-35-3Relevant academic research and scientific papers
A practical synthesis of 3(S)-methyl-heptanoic acid from (S)-citronellol
Breitenbach, Ralph,Chiu, Charles K.-F.,Massett, Stephen S.,Meltz, Morgan,Murtiashaw, C. William,Pezzullo, Susan L.,Staigers, Thomas
, p. 435 - 442 (1996)
Chiral 3-methyl-heptanoic acid is readily accessible by functional group manipulation of optically active citronellol. In principle, this approach is general and could be applied to the synthesis of chiral 3-methyl-alkanoic acids seven carbon atoms in length and longer.
Synthesis of a comprehensive polyprenol library for the evaluation of bacterial enzyme lipid substrate specificity
Wu, Baolin,Woodward, Robert,Wen, Liuqing,Wang, Xuan,Zhao, Guohui,Wang, Peng George
, p. 8162 - 8173 (2014/01/06)
Polyprenols, a universal class of glycan-carrier lipids, play important roles in glycan biosynthesis in wide variety of living organisms. The chemical synthesis of natural polyisoprenols such as undecaprenol and dolichols, and even more so the synthesis o
Synthesis of all the stereoisomers of 6-methyl-2-octadecanone, 14-methyl-2-octadecanone, and 6,14-dimethyl-2-octadecanone, sex pheromone components of the Lyclene dharma dharma moth, from the enantiomers of citronellal
Shikichi, Yasumasa,Mori, Kenji
, p. 1943 - 1951 (2013/01/15)
The enantiomers of citronellal were converted to all the stereoisomers of 6-methyl-2-octadecanone, 14-methyl-2-octadecanone, and 6,14-dimethyl-2- octadecanone, the female-produced sex pheromone components of the Lyclene dharma dharma moth. Three wellestablished procedures, the Wittig reaction, alkylation of alkynes, and acetoacetic ester synthesis, were employed for the carbon-carbon bond formation to connect the building blocks.
A SIMPLE AND EFFICIENT SYNTHESIS OF 3-METHYL-6-(1-METHYLETHENYL)-9-DECEN-1-YL ACETATE A COMPONENT OF THE CALIFORNIA RED SCALE PHEROMONE
Calo, Vincenzo,Lopez, Luigi,Fiandanese, Vito
, p. 577 - 579 (2007/10/02)
A diastereomeric mixture of (3S,6R) and (3S,6S) 3-methyl-6-(1-methylethenyl)-9-decen-1-yl acetate 1(a,b) has been synthesized in high yield starting from (S)-(-)-citronellol.The key step of the synthesis is the regioselective coupling of the benzothiazole
