138616-62-3Relevant academic research and scientific papers
Palladium-Catalyzed Tandem γ-Arylation/Aromatization of Cyclohex-2-En-1-One Derivatives: A Route to 3,4-Dihydroanthracen-1(2H)-Ones
Feng, Chen-Guo,Fu, Jian-Guo,Lin, Guo-Qiang,Song, Yi-Kang,Xu, Si-Yu,Zhang, Shu-Sheng
supporting information, p. 3001 - 3005 (2021/05/07)
An intramolecular palladium-catalyzed tandem γ-arylation/aromatization reaction of cyclohex-2-en-1-one derivatives was developed. This work provides a simple and efficient approach for the construction of substituted 3,4-dihydroanthracen-1(2H)-ones in good yields with a broad substrate scope. (Figure presented.).
Regioselective Aryl Radical Cyclization. 1. Stereocontrolled Synthesis of Linearly Condensed Hydroaromatic Carbocyclic Systems through 6-endo-ring Closures
Pal, Sitaram,Mukhopadhyaya, Jayanta K.,Ghatak, Usha Ranjan
, p. 2687 - 2694 (2007/10/02)
The stereocontrolled synthesis of trans-octahydroanthracenes 3, 11a-c, and 14a-c and trans-octahydro-5aH-cycloheptanaphthalene (27) through implementation of an efficient and highly regioselective 6-endo-trig-aryl radical cyclization of the respective 2-(o-bromoaryl)-1-methylenecyclohexanes 2, 10a-c, and 13a-c and 2-(o-bromobenzyl)-1-methylenecycloheptane (41) with tri-n-butyltin hydride id described.The radical cyclization of 2-(o-bromobenzyl)-1-methylenecyclopentane (43), in contrast, produced a mixture of the cis- and trans-hexahydro-1H-benzindenes (38) and (37).
A Highly Regioselective 6-endo-Aryl Radical Cyclisation: Stereocontrolled Synthesis of trans-Octahydroanthracenes
Pal, Sitaram,Mukherjee, Monika,Podder, Debi,Mukherjee, Alok K.,Ghatak, Usha Ranjan
, p. 1591 - 1593 (2007/10/02)
The stereocontrolled synthesis of trans-octahydroanthracenes 3, 11 and 14 through implementation of an efficient and highly regioselective 6-endo-trig-aryl radical cyclisation of the respective 2-(o-bromobenzyl)-1-methylenecyclohexanes 2, 10 and 13, with
