138749-96-9

Basic information

• Product Name: t-3-<(benzyloxy)methyl>-2-methyl-r-1-cyclohexanol
• Synonyms: t-3-<(benzyloxy)methyl>-2-methyl-r-1-cyclohexanol
• CAS NO: 138749-96-9
• Molecular Weight: 234.338
• Mol File: 138749-96-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: t-3-<(benzyloxy)methyl>-2-methyl-r-1-cyclohexanol(CAS DataBase Reference)
• NIST Chemistry Reference: t-3-<(benzyloxy)methyl>-2-methyl-r-1-cyclohexanol(138749-96-9)
• EPA Substance Registry System: t-3-<(benzyloxy)methyl>-2-methyl-r-1-cyclohexanol(138749-96-9)

Safety Data

• Hazardous Substances Data: 138749-96-9(Hazardous Substances Data)

Upstream product

• 110-83-8 cyclohexene 
• 137946-46-4 3-<(benzyloxy)methyl>cyclohexene 
• 138630-58-7 t-3-<(benzyloxy)methyl>-t-2-bromo-r-1-cyclohexanol 
• 100-39-0 benzyl bromide 
• 25662-37-7 methyl cyclohex-2-en-1-carboxylate 
• 103668-33-3 3-hydroxymethylcyclohexene 
• 15681-48-8 lithium dimethylcuprate 
• 138749-89-0 t-3-<(benzyloxy)methyl>-r-1,2-epoxycyclohexane 

Relevant articles and documents

Regiochemical Control of the Ring Opening of 1,2-Epoxides by Means of Chelating Processes. 4. Synthesis and Reactions of the cis- and trans-Oxides Derived from 3-cyclohexene

The synthesis and nucleophilic addition reactions of diastereoisomeric title epoxides cis-7 and trans-8 were studied.While the ring-opening reactions of trans epoxide 8 are rationalized by means of steric, stereoelectronic, and conformational arguments, the analogous reactions of cis epoxide 7 indicate the ability of this isomer to react through chelated intermediates when metal salt catalyst is used.In 7 chelation reaction conditions led to a significant increase of nucleophilic attack on the C-1 oxirane carbon; the lack of reversal of the regiochemistry of the ring opening on passing from nonchelating to chelating reaction conditions suggests that cis epoxide 7 reacts through its more stable conformation in both of the two different operating conditions.