13884-96-3Relevant academic research and scientific papers
Preparation and chemistry of phosphoranyl-derived iodanes
Zhdankin, Viktor V.,Maydanovych, Olena,Herschbach, Jon,Bruno, Jessica,Matveeva, Elena D.,Zefirov, Nikolai S.
, p. 1018 - 1023 (2007/10/03)
The preparation and chemistry of novel phosphoranyl-derived λ3-iodanes is reported. The phosphoranyl-derived phenyliodonium sulfonates were prepared in good yields by the reaction of stabilized phosphonium ylides [1-triphenylphosphoranylidene-2-propanone, methyl(triphenylphosphoranylidene)acetate, (triphenylphosphoranylidene)acetaldehyde, and (triphenylphosphoranylidene)acetonitrile] with the pyridinium complex of iodobenzene ditriflate or with [hydroxy(tosyloxy)-iodo]benzene under mild conditions. These compounds represent a potentially useful class of reagents that combine in one molecule synthetic advantages of a phosphonium ylide and an iodonium salt. Specifically, phosphorane-derived phenyliodonium tosylates can react with soft nucleophiles, such as iodide, bromide, benzenesulfinate, and thiophenolate anions, with a selective formation of the respective α-functionalized phosphonium ylides, which can be further converted to alkenes by the Wittig reaction with benzaldehyde. The phosphoranyl-derived benziodoxoles can be prepared by the reaction of 1-acetoxybenziodoxole with stabilized phosphonium ylides. An unusual ligand exchange on the iodine(III) center resulting in the substitution of a carbon ligand with an oxygen ligand was observed in the reaction of these compounds with strong acids.
Preparation, structure, and chemistry of phosphorane-derived phenyliodonium sulfonates
Zhdankin, Viktor V.,Maydanovych, Olena,Herschbach, Jon,Bruno, Jessica,Matveeva, Elena D.,Zefirov, Nikolai S.
, p. 2359 - 2361 (2007/10/03)
New triphenylphosphorane-derived phenyliodonium triflates and tosylates were prepared by the reaction of the appropriate iodosobenzene sulfonate with stabilized phosphonium ylides. Structure of the triflate derivative was determined by a single-crystal X-
PYROLYSIS OF α-ACYL,α-THIO PHOSPHORANES THIOACETYLENES
Braga, Antonio L.,Comasseto, Joao V.,Petragnani, Nicola
, p. 1111 - 1114 (2007/10/02)
Pyrolysis of α-acyl,α-thio phosphoranes affords thioacetylenes in a good yield.The thio acethylenes are precursors of terminal and alkyl disubstituted acetylenes.
