1395463-53-2Relevant academic research and scientific papers
Pincer-Nickel-Catalyzed Cross-Coupling of Aryl Sulfamates with Arylzinc Chlorides
Tao, Jian-Long,Wang, Zhong-Xia
, p. 6534 - 6540 (2015/10/19)
The nickel N,N,N-pincer complex 2 was demonstrated to effectively catalyze the cross-coupling of aryl sulfamates with arylzinc chlorides under mild conditions. The reaction is suitable for a wide range of substrates, and tolerates various functional groups. A nickel N,N,N-pincer complex effectively catalyzes the cross-coupling of aryl sulfamates with arylzinc chlorides under mild conditions. The reaction is suitable for a wide range of substrates, and tolerates various functional groups.
Direct cross-coupling of benzyl alcohols to construct diarylmethanes via palladium catalysis
Cao, Zhi-Chao,Yu, Da-Gang,Zhu, Ru-Yi,Wei, Jiang-Bo,Shi, Zhang-Jie
supporting information, p. 2683 - 2686 (2015/03/05)
A direct arylation to furnish diarylmethanes from benzyl alcohols was realized through Pd(PPh3)4-catalyzed Suzuki-Miyaura coupling via benzylic C-O activation in the absence of any additives. The arylation is compatible with various functional groups. This development provides an atom- and step-economic way to approach a diarylmethane scaffold under mild and environmentally benign conditions. This journal is
Direct arylation/alkylation/magnesiation of benzyl alcohols in the presence of grignard reagents via Ni-, Fe-, or Co-catalyzed sp3 C-O Bond activation
Yu, Da-Gang,Wang, Xin,Zhu, Ru-Yi,Luo, Shuang,Zhang, Xiao-Bo,Wang, Bi-Qin,Wang, Lei,Shi, Zhang-Jie
, p. 14638 - 14641 (2012/11/07)
Direct application of benzyl alcohols (or their magnesium salts) as electrophiles in various reactions with Grignard reagents has been developed via transition metal-catalyzed sp3 C-O bond activation. Ni complex was found to be an efficient catalyst for the first direct cross coupling of benzyl alcohols with aryl/alkyl Grignard reagents, while Fe, Co, or Ni catalysts could promote the unprecedented conversion of benzyl alcohols to benzyl Grignard reagents in the presence of nhexylMgCl. These methods offer straightforward pathways to transform benzyl alcohols into a variety of functionalities.
