140148-51-2

Upstream product

• 100-39-0 benzyl bromide 
• 140148-50-1 (-)-3,4-di-O-allyl-5,6-di-O-benzyl-1,2-O-cyclohexylidene-myo-inositol 
• 145789-53-3 (+)-3,4-di-O-allyl-1,2:5,6-di-O-cyclohexylidene-myo-inositol 
• 139978-96-4 (+)-3,4-di-O-allyl-1,2-O-cyclohexylidene-myo-inositol 
• 6763-49-1 (+/-)-1,2:5,6-dicyclohexylidene-myo-inositol 
• 33021-17-9 (-)-2,3:4,5-di-O-cyclohexylidene-myo-inositol 
• 116786-69-7 (+)-3,4-di-O-allyl-5,6-di-O-benzyl-myo-inositol 
• 106-95-6 allyl bromide 
• 818-08-6 di(n-butyl)tin oxide 
• 98906-33-3 (±)-1,4-di-O-allyl-2,3-O-isopropylidene-myo-inositol 
• 98906-32-2 (±)-1,4-di-O-allyl-2,3:5,6-di-O-isopropylidene-myo-inositol 
• 51548-88-0 (+/-)-1,2:4,5-di-O-isopropylidene-myo-inositol 
• 112204-06-5 (+/-)-3,6-di-O-allyl-4,5-di-O-benzyl-1,2-O-cyclohexylidene-myo-inositol 
• 112204-04-3 3,6-di-O-allyl-1,2:4,5-di-O-cyclohexylidene-myo-inositol 

Downstream Products

• 120051-10-7 (2S,3R,4R,5S,6R)-2,3,6-Tris-allyloxy-4,5-bis-benzyloxy-cyclohexanone 
• 120051-07-2 C₂₉H₃₅FO₅ 
• 111392-19-9 C₃₀H₃₈O₆ 
• 115509-76-7 (-)-1D-2,5,6-tri-O-benzyl-myo-inositol 
• 103476-24-0 1D-myo-inositol 1,3,4-triphosphate hexapotassium salt 
• 93133-76-7 D-Inositol 1,3,4-triphosphate 
• 115510-58-2 (+)-1D-2,5,6-tri-O-benzyl-1,3,4-tris(dibenzylphospho)-myo-inositol 
• 140148-52-3 (+)-1,3,4-tri-O-allyl-2,5,6-tri-O-benzyl-myo-inositol 
• 114342-70-0 DL-2,5,6-tri-O-benzyl-1,3,4-tris(dibenzylphospho)-myo-inositol 
• 120051-13-0 Phosphoric acid dibenzyl ester (1S,2R,4S,5R,6R)-5,6-bis-benzyloxy-2,4-bis-(bis-benzyloxy-phosphoryloxy)-3,3-difluoro-cyclohexyl ester 
• 120051-09-4 Phosphoric acid dibenzyl ester (1R,2S,3S,4R,5S,6S)-2,3-bis-benzyloxy-4,5-bis-(bis-benzyloxy-phosphoryloxy)-6-fluoro-cyclohexyl ester 
• 120051-04-9 2,2-difluoro-2-deoxy-DL-myo-inositol (1,3,4)-triphosphate 
• 120051-03-8 hexasodium 2-fluoro-2-deoxy-DL-myo-inositol (1,3,4)-triphosphate 
• 120051-11-8 C₂₉H₃₄F₂O₅ 

Relevant academic research and scientific papers

An efficient chemoenzymic access to optically active myo-inositol polyphosphates

The 1,4,5-tris-, 1,3,4-tris-, and 1,3,4,5-tetrakis-phosphates of 1D-myo-inositol have been prepared in their enantiomerically pure forms from the two enantiomers of 1,2:5,6-di-O-cyclohexylidene-myo-inositol. A facile enzymic preparation is also described

AN EFFICIENT ROUTE TO D-MYO-INOSITOL 1,3,4-TRIPHOSPHATE AND D-MYO-INOSITOL 1,3,4,5-TETRAKISPHOSPHATE

Multigram quantities of the title compounds in their enantiomerically-pure forms have been prepared by employing a chiral precursor which can be obtained via a facile enzymatic process.

THE TOTAL SYNTHESIS OF myo-INOSITOL POLYPHOSPHATES

Total synthesis of the individual enentiomers of myo-inositol 4-phosphate (15), myo-inositol 1,4-biphosphate (2) and myo-inositol 1,4,5-triphosphate (1), together with syntheses of racemic myo-inositol 1,3,4-triphosphate (4) and myo-inositol 2,4,5-triphos

The Allyl Group for Protection in Carbohydrate Chemistry. Part 18. Allyl and Benzyl Ethers of myo-Inositol. Intermediates for the Synthesis of myo-Inositol Triphosphates

Racemic 1,2:4,5-di-O-isopropylidene-myo-inositol was converted into racemic 1,2,4-tri-O-benzyl-myo-inositol, 1,2,4-tri-O-p-methoxybenzyl-myo-inositol and 2,4,5-tri-O-benzyl-myo-inositol using allyl groups for 'temporary' protection.The benzyl ethers are required as intermediates for the synthesis of the 'second messenger', inositol 1,4,5-triphosphate and its metabolite, inositol 1,3,4-triphosphate. 1,2,3,4-Tetra-O-benzyl-myo-inositol, and its two monoallyl and monoprop-1-enyl ethers, were also prepared as model compounds for phosphorylation studies of the vicinal 5,6-diol system which occurs in 1,2,4-tri-O-benzyl-myo-inositol.

SYNTHESIS OF RACEMIC MYO-INOSITOL 1,3,4-TRIPHOSPHATE VIA A PHOSPHITE-TRIESTER APPROACH

Phosphitylation of (+/-)- 2,4,5-tri-O-benzyl-myo-Inositol with bis(2-cyanoethyl)chlorophosphine gave, after oxidation followed by basic hydrolysis and subsequently hydrogenolysis, (+/-)-myo-Inositol 1,3,4-triphosphate.