1401733-65-0Relevant academic research and scientific papers
Palladium-catalyzed direct acylation of ketoximes and aldoximes from the alcohol oxidation level through C-H bond activation
Sharma, Satyasheel,Kim, Minyoung,Park, Jihye,Kim, Mirim,Kwak, Jong Hwan,Jung, Young Hoon,Oh, Joa Sub,Lee, Youngil,Kim, In Su
, p. 6656 - 6665 (2013)
A highly efficient palladium-catalyzed oxidative ortho-acylation of O-methyl ketoximes and O-methyl aldoximes with benzylic and aliphatic alcohols from the alcohol oxidation level is described. This protocol potentially provides new opportunities to use readily available alcohols as starting materials for catalytic reactions, and represents a catalytic alternative to transcend the barriers imposed by classical Friedel-Crafts acylation. A highly efficient palladium-catalyzed oxidative ortho-acylation of O-methyl ketoximes and O-methyl aldoximes with benzylic and aliphatic alcohols from the alcohol oxidation level is described. Copyright
NHPI and palladium cocatalyzed aerobic oxidative acylation of arenes through a radical process
Liang, Yu-Feng,Wang, Xiaoyang,Tang, Conghui,Shen, Tao,Liu, Jianzhong,Jiao, Ning
, p. 1416 - 1419 (2016/01/25)
The NHPI and palladium cocatalyzed radical oxidative acylation of arenes with aldehydes and alcohols as acyl equivalents via selective C-H functionalization has been described. Molecular oxygen, the most environmentally friendly oxidant, was used as the terminal oxidant in this catalytic cycle.
Palladium-Catalyzed Oxidative Direct ortho-C-H Acylation of Arenes with Aldehydes under Aqueous Conditions
Xiao, Fuhong,Chen, Shuqing,Huang, Huawen,Deng, Guo-Jun
supporting information, p. 7919 - 7925 (2015/12/24)
Palladium-catalyzed ortho-acylation of arenes with aldehydes in the presence of tert-butyl hydroperoxide (TBHP) as the oxidant under aqueous conditions has been demonstrated. The acylation reaction exhibits excellent regioselectivity and wide functional g
Palladium-catalyzed decarboxylative acylation of O-methyl ketoximes with α-keto acids
Kim, Minyoung,Park, Jihye,Sharma, Satyasheel,Kim, Aejin,Park, Eonjeong,Kwak, Jong Hwan,Jung, Young Hoon,Kim, In Su
, p. 925 - 927 (2013/02/23)
A mild, practical and efficient palladium-catalyzed decarboxylative ortho-acylation of O-methyl ketoximes with α-keto acids via C-H bond activation is described. In these reactions, a broad range of O-methyl ketoximes and α-keto acids undergoes the decarboxylative cross-coupling reactions with high selectivities and good tolerance. The Royal Society of Chemistry 2013.
Four tandem C-H activations: A sequential C-C and C-O bond making via a Pd-catalyzed cross dehydrogenative coupling (CDC) approach
Guin, Srimanta,Rout, Saroj Kumar,Banerjee, Arghya,Nandi, Shyamapada,Patel, Bhisma K.
, p. 5294 - 5297,4 (2020/09/02)
An unprecedented aroylation at the ortho C-H bond with respect to a directing group has been accomplished via a Pd(II)-catalyzed cross dehydrogenative coupling approach using alkylbenzene as the synthetic equivalent of an aroyl moiety. The reaction proceeds through sequential C-C and C-O bond making at the expense of four consecutive C-H bond cleavages (three sp 3 benzylic C-H's and one sp2 arene C-H) to selectively install an aroyl functionality at the proximal site of substrates containing various directing groups.
