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14026-45-0

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14026-45-0 Usage

General Description

6-Nitro-1,2,3,4-tetrahydroquinoline is a chemical compound with the molecular formula C9H9NO2. It is a nitro derivative of tetrahydroquinoline, which is a bicyclic heterocyclic compound. This chemical has a nitro group attached to the 6th position of the quinoline ring and is commonly used as an intermediate in the synthesis of various pharmaceuticals and organic compounds. It has been studied for its potential biological and pharmacological activities, including its antimicrobial and antitumor properties. Additionally, it has also been investigated for its use as a building block in the synthesis of organic molecules. Overall, 6-Nitro-1,2,3,4-tetrahydroquinoline is an important chemical with diverse applications in the pharmaceutical and chemical industries.

Check Digit Verification of cas no

The CAS Registry Mumber 14026-45-0 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,4,0,2 and 6 respectively; the second part has 2 digits, 4 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 14026-45:
(7*1)+(6*4)+(5*0)+(4*2)+(3*6)+(2*4)+(1*5)=70
70 % 10 = 0
So 14026-45-0 is a valid CAS Registry Number.
InChI:InChI=1/C9H10N2O2/c12-11(13)8-3-4-9-7(6-8)2-1-5-10-9/h3-4,6,10H,1-2,5H2

14026-45-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 13, 2017

Revision Date: Aug 13, 2017

1.Identification

1.1 GHS Product identifier

Product name 6-Nitro-1,2,3,4-tetrahydroquinoline

1.2 Other means of identification

Product number -
Other names 6-Nitro-tetrahydrochinolin

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:14026-45-0 SDS

14026-45-0Relevant articles and documents

Method for selective catalytic hydrogenation of aromatic heterocyclic compounds in non-hydrogen participation manner

-

Paragraph 0025-0029; 0168-0172, (2021/08/19)

The invention discloses a method for selective catalytic hydrogenation of aromatic heterocyclic compounds in a non-hydrogen participation manner. The method comprises the following steps: by taking 1, 5-cyclooctadiene iridium chloride dimer as a catalyst and phenylsilane as a hydrogen source, carrying out stirring reaction under mild conditions without adding a ligand, namely catalytically hydrogenating the aromatic heterocyclic compounds to obtain hydrogenated products of the aromatic heterocyclic compounds. The method has the advantages of low cost, mild reaction conditions, high selectivity and the like, and special equipment such as a high-pressure kettle and the like and high-temperature conditions which are required when hydrogen is used are avoided.

Utilization of renewable formic acid from lignocellulosic biomass for the selective hydrogenation and/or N-methylation

Zhou, Chao-Zheng,Zhao, Yu-Rou,Tan, Fang-Fang,Guo, Yan-Jun,Li, Yang

, p. 4724 - 4728 (2021/09/06)

Lignocellulosic biomass is one of the most abundant renewable sources in nature. Herein, we have developed the utilization of renewable formic acid from lignocellulosic biomass as a hydrogen source and a carbon source for the selective hydrogenation and further N-methylation of various quinolines and the derivatives, various indoles under mild conditions in high efficiencies. N-methylation of various anilines is also developed. Mechanistic studies indicate that the hydrogenation occurs via a transfer hydrogenation pathway.

Activation of Quinolines by Cationic Chalcogen Bond Donors

Huber, S. M.,Steinke, T.,Wonner, P.

supporting information, p. 1673 - 1678 (2019/08/26)

The application of already established as well as novel selenium- and sulfur-based cationic chalcogen bond donors in the catalytic activation of quinoline derivatives is presented. In the presence of selected catalysts, rate accelerations of up to 2300 compared to virtually inactive reference compounds are observed. The catalyst loading can be reduced to 1 molpercent while still achieving nearly full conversion for electron-poor and electron-rich quinolines. Contrary to expectations, preorganized catalysts were less active than the more flexible variants.

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