140462-99-3

Basic information

• Product Name: (Z)-O-methyl-4-methoxybenzohydroximoyl bromide
• Synonyms: (Z)-O-methyl-4-methoxybenzohydroximoyl bromide
• CAS NO: 140462-99-3
• Molecular Weight: 244.088
• Mol File: 140462-99-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (Z)-O-methyl-4-methoxybenzohydroximoyl bromide(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-O-methyl-4-methoxybenzohydroximoyl bromide(140462-99-3)
• EPA Substance Registry System: (Z)-O-methyl-4-methoxybenzohydroximoyl bromide(140462-99-3)

Safety Data

• Hazardous Substances Data: 140462-99-3(Hazardous Substances Data)

Upstream product

• 100-07-2 4-methoxy-benzoyl chloride 

Downstream Products

• 70286-37-2 4-methoxy-benzaldehyde-(O-methyl-seqtrans-oxime ) 
• 874-90-8 4-methoxybenzonitrile 
• 140463-02-1 (E)-O-methyl-4-methoxybenzohydroximoyl bromide 
• 690663-32-2 (Z)-N,4-dimethoxybenzenecarboximidoyl fluoride 
• 690663-29-7 methyl (Z)-O-methyl-4-methoxybenzohydroximate 
• 701975-73-7 2-propenyl (Z)-N,4-dimethoxybenzimidate 
• 701976-00-3 [(4R,5S)-4-(4-methoxyphenyl)-2-oxo-1,3-oxazolidin-5-yl]methyl (1S,4R)-4,7,7-trimethyl-3-oxo-2-oxabicyclo[2.2.1]heptane-1-carboxylate 
• 701975-99-7 [(4S,5R)-4-(4-methoxyphenyl)-2-oxo-1,3-oxazolidin-5-yl]methyl (1S,4R)-4,7,7-trimethyl-3-oxo-2-oxabicyclo[2.2.1]heptane-1-carboxylate 
• 701975-81-7 (Z)-2-hydroxy-1-(4-methoxyphenyl)-3-buten-1-one O-methyloxime 
• 220736-25-4 trans-5-(hydroxymethyl)-4-(4-methoxyphenyl)-1,3-oxazolidin-2-one 
• 220736-25-4 (4R,5S)-5-(hydroxymethyl)-4-(4-methoxyphenyl)-1,3-oxazolidin-2-one 
• 237736-11-7 (-)-(4S,5R)-5-hydroxymethyl-4-(4-methoxyphenyl)-1,3-oxazolidin-2-one 
• 1224174-93-9 4-methoxy-O-methylbenzohydroximoyl azide 
• 87861-04-9 (Z)-4-methoxybenzaldehyde O-methyloxime 

Relevant articles and documents

Imino 1,2-Wittig rearrangement of hydroximates and its application to synthesis of cytoxazone

The imino 1,2-Wittig rearrangement of hydroximates provides a novel method for the construction of 2-hydroxyoxime ethers. Upon treatment with LDA, Z-hydroximates smoothly underwent stereoselective rearrangement to give Z-2-hydroxyoxime ethers in good yield, which were converted into amino alcohols. On the other hand, the rearrangement of E-hydroximates gave a mixture of E- and Z-2-hydroxyoxime ethers. This method was successfully applied to a practical synthesis of cytoxazone.