140675-27-0Relevant articles and documents
Enantio- and Regioselective NiH-Catalyzed Reductive Hydroarylation of Vinylarenes with Aryl Iodides
He, Yuli,Liu, Chuang,Yu, Lei,Zhu, Shaolin
supporting information, p. 21530 - 21534 (2020/10/02)
A highly enantio- and regioselective hydroarylation process of vinylarenes with aryl halides has been developed using a NiH catalyst and a new chiral bis imidazoline ligand. A broad range of structurally diverse, enantioenriched 1,1-diarylalkanes, a structure found in a number of biologically active molecules, have been obtained with excellent yields and enantioselectivities under extremely mild conditions.
Alkene functionalization for the stereospecific synthesis of substituted aziridines by visible-light photoredox catalysis
Yu, Wan-Lei,Chen, Jian-Qiang,Wei, Yun-Long,Wang, Zhu-Yin,Xu, Peng-Fei
supporting information, p. 1948 - 1951 (2018/03/01)
A novel strategy involving visible-light-induced functionalization of alkenes for the synthesis of substituted aziridines was developed. The readily prepared N-protected 1-aminopyridinium salts were used for the generation of N-centered radicals. This approach allowed the synthesis of aziridines bearing various functional groups with excellent diastereoselectivity under mild conditions. Moreover, this protocol was successfully applied to prepare structurally diverse nitrogen-containing frameworks.
Palladium-catalyzed coupling reaction of alkenylgalliums with aryl halides
Mikami, Satoshi,Yorimitsu, Hideki,Oshima, Koichiro
, p. 1137 - 1139 (2007/10/03)
Treatment of aryl halides with alkenylgallium dichloride, prepared from GaCl3 and alkenylmagnesium bromide, in the presence of a catalytic amount of palladium provided cross-coupling products in good yields.
