141020-13-5

Basic information

• Product Name: Methyl-2,3,6-tri-O-benzoyl-4-O-phenoxythiocarbonyl-α-D-galactopyranosid
• Synonyms: Methyl-2,3,6-tri-O-benzoyl-4-O-phenoxythiocarbonyl-α-D-galactopyranosid
• CAS NO: 141020-13-5
• Molecular Weight: 642.683
• Mol File: 141020-13-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Methyl-2,3,6-tri-O-benzoyl-4-O-phenoxythiocarbonyl-α-D-galactopyranosid(CAS DataBase Reference)
• NIST Chemistry Reference: Methyl-2,3,6-tri-O-benzoyl-4-O-phenoxythiocarbonyl-α-D-galactopyranosid(141020-13-5)
• EPA Substance Registry System: Methyl-2,3,6-tri-O-benzoyl-4-O-phenoxythiocarbonyl-α-D-galactopyranosid(141020-13-5)

Safety Data

• Hazardous Substances Data: 141020-13-5(Hazardous Substances Data)

Upstream product

• 3601-36-3 methyl 2,3,6-tri-O-benzoyl-α-D-galactopyranoside 
• 1005-56-7 phenylcarbonochloridothioate 

Downstream Products

• 141020-17-9 Benzyl-O-(2,3,6-tri-O-benzoyl-4-desoxy-α-D-xylo-hexopyranosyl)-(1->3)-2-acetamido-4,6-O-benzyliden-2-desoxy-α-D-galactopyranosid 
• 141020-17-9 Benzyl-O-(2,3,6-tri-O-benzoyl-4-desoxy-β-D-xylo-hexopyranosyl)-(1->3)-2-acetamido-4,6-O-benzyliden-2-desoxy-α-D-galactopyranosid 
• 141020-18-0 Benzyl-O-(2,3,6-tri-O-benzoyl-4-desoxy-β-D-xylo-hexopyranosyl)-(1->3)-2-acetamido-4,6-di-O-acetyl-2-desoxy-α-D-galactopyranosid 
• 141020-16-8 O-(2,3,6-Tri-O-benzoyl-4-desoxy-β-D-xylo-hexopyranosyl)trichloroacetamidat 
• 141020-14-6 1-O-Acetyl-2,3,6-tri-O-benzoyl-4-desoxy-α-D-xylo-hexopyranose 
• 141020-19-1 Benzyl-O-(4-desoxy-β-D-xylo-hexopyranosyl)-(1->3)-2-acetamido-2-desoxy-α-D-galactopyranosid 
• 151073-10-8 2,3,6-Tri-O-benzoyl-4-desoxy-D-xylo-hexose 
• 141020-15-7 2,3,6-Tri-O-benzoyl-4-desoxy-α-D-xylo-hexopyranosyliodid 
• 849132-36-1 phenyl 2,3,6-tri-O-acetyl-4-deoxy-1-thio-β-D-xylo-hexoside 
• 13264-03-4 Methyl 2,3,6-tri-O-acetyl-4-deoxy-α-D-glucopyranoside 
• 13241-00-4 methyl 4-deoxy-α-D-xylo-hexopyranoside 
• 19488-41-6 Methyl-2,3,6-tri-O-benzoyl-4-desoxy-α-D-xylo-hexopyranosid 

Relevant articles and documents

From glycoside hydrolases to thioglycoligases: The synthesis of thioglycosides

The treatment of various glycosyl acceptors, each containing a reactive thiol group, with the appropriate glycosyl donor and a glycoside hydrolase or glycosynthase, failed to yield any thioglycosides - only the products of O-glycosylation were formed. However, thioglycosides were formed when a thioglycoligase was used to mediate the reaction between acceptor and donor. In fact, pyranose acceptors possessing a thiol group at C3, C4 or C6 (but not C2) were all capable of conversion into thioglycosides. Some comment is given regarding the mechanism of the various processes.