14112-98-2Relevant articles and documents
A Microbial Synthesis of R and S-9-Hydroxy-(E)-2-Decenoic Acid(9-HDA), A Queen Honeybee Pheromone
Gu, Jian-Xing,Li, Zu-Yi,Lin, Guo-Qiang
, p. 1523 - 1524 (1992)
(R,E)-9-hydroxy-2-decenoic acid (9-HDA) and its (S,E)-isomer have been prepared by using an organic-microbial approach.
On the Water Content of Micelles: Infrared Spectroscopic Studies
Casal, H. L.
, p. 5203 - 5205 (1988)
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Diaper,D.G.M.
, p. 2819 - 2824 (1966)
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Selective C-C Bond Cleavage of Cycloalkanones by NaNO2/HCl
He, Tianyu,Chen, Dengfeng,Qian, Shencheng,Zheng, Yu,Huang, Shenlin
supporting information, p. 6525 - 6529 (2021/09/02)
A novel selective fragmentation of cycloalkanones by NaNO2/HCl has been established. The C-C bond cleavage reaction proceeds smoothly under mild conditions, selectively affording versatile keto acids or oxime acids. The methodology can streamline the synthesis of valuable chiral molecules and isocoumarins from readily available feedstocks.
Analytical methodology for determination of organic aerosol functional group distributions
Kalafut-Pettibone, Alicia J,McGivern, W. Sean
, p. 3553 - 3560 (2013/05/22)
Secondary organic aerosol (SOA) particles result from the condensation of oxidized volatile organic compounds (VOC) and consist of a complex mixture that is not conducive to complete compositional analysis. We present a simple methodology for determining the quantities of aldehydes and ketones, alcohols, and carboxylic acids in such samples via derivatization and high-performance liquid chromatography (HPLC) with ultraviolet-visible absorption detection and tandem mass spectrometry (MS/MS). Useful concentration ranges are presented with an examination of the specificity of these compounds in multiply substituted systems. Such data are valuable in modeling the formation of laboratory-generated aerosols and in identifying point sources of field-collected aerosol samples. Calibration curves on standard samples, MS/MS transitions, including collisionally induced dissociation (CID) products, and a quantitative examination of the specificity of the derivatization reagents toward multiple functional groups are presented for a series of aliphatic standard samples. These methods are then applied to filter extracts from SOA derived from 1-iodooctane photolysis at 254 nm to demonstrate the methodology on a complex system. Ultimately, this methodology enables the measurement of variations in the chemical nature of the oxygen within an SOA particle, providing a distribution of functional group concentrations. This article not subject to U.S. Copyright. Published 2013 by the American Chemical Society.