141249-69-6Relevant articles and documents
An Effective [FeIII(TF4DMAP)Cl] Catalyst for C-H Bond Amination with Aryl and Alkyl Azides
Du, Yi-Dan,Xu, Zhen-Jiang,Zhou, Cong-Ying,Che, Chi-Ming
supporting information, p. 895 - 899 (2019/02/14)
[FeIII(TF4DMAP)Cl] can efficiently catalyze intermolecular sp3 C-H amination using aryl azides and intramolecular sp3 C-H amination of alkyl azides in moderate-to-high product yields. At catalyst loading down to 1 mol %, the reactions display high chemo- and regioselectivity with broad substrate scope and are effective for late-stage functionalization of complex natural/bioactive molecules.
