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1423-15-0

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1423-15-0 Usage

General Description

1-Azido-2,3,4,5,6-pentafluorobenzene is a chemical compound with the molecular formula C6F5N3. It is a benzene derivative that contains a pentafluorophenyl group and an azide functional group. 1-azido-2,3,4,5,6-pentafluorobenzene is highly reactive and is commonly used as a reagent in organic synthesis, particularly in the preparation of other azide-containing compounds. The pentafluorophenyl group provides electron-withdrawing properties, making it useful in reactions involving nucleophilic substitution and aromatic substitution. The azide group is known for its ability to undergo the Staudinger reaction, a useful synthetic transformation in organic chemistry. Due to its potential hazards and high reactivity, 1-azido-2,3,4,5,6-pentafluorobenzene should be handled with care and stored and utilized according to proper safety protocols.

Check Digit Verification of cas no

The CAS Registry Mumber 1423-15-0 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 1,4,2 and 3 respectively; the second part has 2 digits, 1 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 1423-15:
(6*1)+(5*4)+(4*2)+(3*3)+(2*1)+(1*5)=50
50 % 10 = 0
So 1423-15-0 is a valid CAS Registry Number.

1423-15-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 15, 2017

Revision Date: Aug 15, 2017

1.Identification

1.1 GHS Product identifier

Product name 1-azido-2,3,4,5,6-pentafluorobenzene

1.2 Other means of identification

Product number -
Other names pentafluorophenylazide

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:1423-15-0 SDS

1423-15-0Relevant articles and documents

Iron (III)-porphyrin Complex FeTSPP as an efficient catalyst for synthesis of tetrazole derivatives via [2?+?3]cycloaddition reaction in aqueous medium

El-Remaily, Mahmoud Abd El Aleem Ali Ali,Elhady

, (2019/06/08)

The metal complex (5,10,15,20-tetrakis-(4-sulfonatophenyl)-porphyrin-iron (III) chloride (FeTSPP) was new employed in an environmentally benign protocol as an efficient catalyst for a “click” chemistry approach for the synthesis of tetrazole and guanindinyltetrazole derivatives via [2?+?3] cycloaddition reaction of nitriles and azide derivatives in aqueous medium. The synthesized compounds were obtained in excellent yield, short reaction times and a recoverable catalyst.

N, N -diethylurea-catalyzed amidation between electron-deficient aryl azides and phenylacetaldehydes

Xie, Sheng,Ramstr??m, Olof,Yan, Mingdi

supporting information, p. 636 - 639 (2015/03/04)

Urea structures, of which N,N-diethylurea (DEU) proved to be the most efficient, were discovered to catalyze amidation reactions between electron-deficient aryl azides and phenylacetaldehydes. Experimental data support 1,3-dipolar cycloaddition between DEU-activated enols and electrophilic phenyl azides, especially perfluoroaryl azides, followed by rearrangement of the triazoline intermediate. The activation of the aldehyde under near-neutral conditions was of special importance in inhibiting dehydration/aromatization of the triazoline intermediate, thus promoting the rearrangement to form aryl amides.

Effective synthesis of chiral N-fluoroaryl aziridines through enantioselective aziridination of alkenes with fluoroaryl azides

Jin, Li-Mei,Xu, Xue,Lu, Hongjian,Cui, Xin,Wojtas, Lukasz,Zhang, X. Peter

supporting information, p. 5309 - 5313 (2013/06/26)

The CoII complex of a D2-symmetric chiral porphyrin ([Co(D2-Por*)], see scheme) is a highly effective catalyst for the enantioselective aziridination of alkenes with fluoroaryl azides. The reaction can be performed at RT w

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