142004-80-6Relevant academic research and scientific papers
A Novel Stereospecific Rearrangement of 3-Substituted B-Homo 5-Azasteroids to Their A-Nor Analogues. Preparation, Stereochemistry, and Conformational Studies
Back, Thomas G.,Chau, Joseph H.-L.,Codding, Penelope W.,Gladstone, Patricia L.,Jones, David H.,et al.
, p. 4110 - 4121 (2007/10/02)
The novel 3α- and 3β-hydroxy-B-homo-5-azasteroid lactams 4 and 5 were prepared from testosterone.When the hydroxyl group in these compounds is converted into a leaving group, rearrangement to the corresponding A-nor azasteroids occurs under a variety of c
