1423-13-8

Basic information

• Product Name: pentafluoronitrosobenzene
• Synonyms: pentafluoronitrosobenzene;1,2,3,4,5-Pentafluoro-6-nitrosobenzene;2,3,4,5,6-Pentafluoro-1-nitrosobenzene
• CAS NO: 1423-13-8
• Molecular Formula: C₆F₅NO
• Molecular Weight: 197.062316
• EINECS: 215-832-1
• Mol File: 1423-13-8.mol
• Article Data: 6

Chemical Properties

• Boiling Point: 202.1°Cat760mmHg
• Flash Point: 61.9°C
• Appearance: /
• Density: 1.68g/cm³
• Vapor Pressure: 0.423mmHg at 25°C
• Refractive Index: 1.44
• CAS DataBase Reference: pentafluoronitrosobenzene(CAS DataBase Reference)
• NIST Chemistry Reference: pentafluoronitrosobenzene(1423-13-8)
• EPA Substance Registry System: pentafluoronitrosobenzene(1423-13-8)

Safety Data

• Hazardous Substances Data: 1423-13-8(Hazardous Substances Data)

Usage

InChI:InChI=1/C6F5NO/c7-1-2(8)4(10)6(12-13)5(11)3(1)9

Upstream product

• 771-60-8 2,3,4,5,6-pentafluoroaniline 
• 3796-31-4 silver pentafluorobenzoate 
• 91978-73-3 Pentafluorbenzoylnitrit 
• 5272-26-4 trifluoro(pentafluorophenyl)silane 

Downstream Products

• 30287-20-8 N-(1,1,2-trimethyl-2-propenylpentafluorophenyl)hydroxylamine 
• 54698-79-2 N-(1-Methyl)-2-propenylpentafluoranilin 
• 4126-86-7 1,2,4,5-Tetrafluor-3-methoxy-6-nitroso-benzol 
• 1800-29-9 decafluoroazoxybenzene 
• 5493-21-0 3-pentafluorophenyl-2-oxa-3-aza-bicyclo[2.2.2]oct-5-ene 
• 2253-45-4 C₁₉H₁₀F₅NO 
• 40474-31-5 2,3,4,5,6-pentafluorophenylazobenzene 
• 1643-71-6 2,3,5,6-tetrafluoro-4-methoxyaniline 
• 22955-57-3 4-amino-2,3,5,6-tetrafluroazobenzene 

Related news

Reaction of pentafluoronitrosobenzene (cas 1423-13-8) with [Os3(CO)11(CH3CN)] and high-performance liquid chromatographic separation of [Os3(CO)11(μ-ONC6F5)], [Os3(CO)9(μ3-NC6F5)2], [Os3(CO)11(CH3CN)] and Os3(CO)1209/27/2019

Reaction of pentafluoronitrosobenzene with [Os3(CO)11(CH3CN)] in THF at room temperature yields a new triosmium cluster, [Os3(CO)11(μ-ONC6F5)] (I), where the pentafluorophenylnitroso ligand has been shown by X-ray crystallography to adopt an unusual bonding mode, with its nitrogen bridging two ...detailed

Reaction of pentafluoronitrosobenzene (cas 1423-13-8) with [Os3H(μ-H) (CO)10(MPh3) ](M = P, As, Sb): Synthesis and X-ray structure of [Os3(μ-H) (CO) 10(PPh3)(ONC6F4O)09/26/2019

The pentafluoronitrosobenzene C6F5NO has been shown from infrared spectral, 19F NMR spectral and single-crystal X-ray diffraction studies to undergo oxidation at the para-position upon reaction with [OS3H(μ-H)(CO)10(PPh3)] to afford [OS3(μ-H)(CO)10(PPh3)(ONC6F4O)](I). The arsenic- and stibine-...detailed

The reaction of pentafluoronitrosobenzene (cas 1423-13-8) with Os3(CO)12: synthesis and X-ray crystal structure of [Os3(CO)9(μ3-NC6F5)2]09/25/2019

The reaction of pentafluoronitrosobenzene with Os3(CO)12 at 125 °C in octane leads to the formation of a new bis(pentafluorophenylimido)triosmium cluster, [Os3(CO)9(μ3- NC6F5)2] (I). Cluster I has been shown by X-ray crystallographic studies to consist of an open triosmium framework capped by ...detailed

Relevant articles and documents

In Situ Formation of an Azo Bridge on Proteins Controllable by Visible Light

Optical modulation of proteins provides superior spatiotemporal resolution for understanding biological processes, and photoswitches built on light-sensitive proteins have been significantly advancing neuronal and cellular studies. Small molecule photoswitches could complement protein-based switches by mitigating potential interference and affording high specificity for modulation sites. However, genetic encodability and responsiveness to nonultraviolet light, two desired properties possessed by protein photoswitches, are challenging to be engineered into small molecule photoswitches. Here we developed a small molecule photoswitch that can be genetically installed onto proteins in situ and controlled by visible light. A pentafluoro azobenzene-based photoswitchable click amino acid (F-PSCaa) was designed to isomerize in response to visible light. After genetic incorporation into proteins via the expansion of the genetic code, F-PSCaa reacts with a nearby cysteine within the protein generating an azo bridge in situ. The resultant bridge is switchable by visible light and allows conformation and binding of CaM to be regulated by such light. This photoswitch should prove valuable in optobiology for its minimal interference, site flexibility, genetic encodability, and response to the more biocompatible visible light.

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The invention relates to an azo aryl urea derivative, and a preparation and an application thereof, and concretely discloses a compound represented by formula (I), or an optical isomer, a cis-trans-isomer or a pharmaceutically acceptable salt thereof, and a preparation method thereof. Definitions of substituent groups in the general formula are described in the specification and claims. The invention further discloses a composition containing the above compound, and an application thereof. The compound has excellent anticancer activity on HepG2 liver cancer cells, MGC803 gastric cancer cells,HCT116 colon cancer and the like.

Preparation, NMR spectra and reactivity of pentafluorophenyltetrafluorosilicates M+-

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