The reaction of pentafluoronitrosobenzene (cas 1423-13-8) with Os3(CO)12: synthesis and X-ray crystal structure of [Os3(CO)9(μ3-NC6F5)2]

Add time:09/25/2019    Source:sciencedirect.com

The reaction of pentafluoronitrosobenzene (cas 1423-13-8) with Os3(CO)12 at 125 °C in octane leads to the formation of a new bis(pentafluorophenylimido)triosmium cluster, [Os3(CO)9(μ3- NC6F5)2] (I). Cluster I has been shown by X-ray crystallographic studies to consist of an open triosmium framework capped by triply bridging pentafluorophenylimido ligands.

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