Reaction of pentafluoronitrosobenzene (cas 1423-13-8) with [Os3H(μ-H) (CO)10(MPh3) ](M = P, As, Sb): Synthesis and X-ray structure of [Os3(μ-H) (CO) 10(PPh3)(ONC6F4O)

Add time:09/26/2019    Source:sciencedirect.com

The pentafluoronitrosobenzene (cas 1423-13-8) C6F5NO has been shown from infrared spectral, 19F NMR spectral and single-crystal X-ray diffraction studies to undergo oxidation at the para-position upon reaction with [OS3H(μ-H)(CO)10(PPh3)] to afford [OS3(μ-H)(CO)10(PPh3)(ONC6F4O)](I). The arsenic- and stibine- analogues of I [(OS3)(μ-H)(CO)10(MPh3)(XONC6F40)l (M = As, Sb)) were also isolated.

We also recommend Trading Suppliers and Manufacturers of pentafluoronitrosobenzene (cas 1423-13-8). Pls Click Website Link as below: cas 1423-13-8 suppliers

Prev:The reaction of pentafluoronitrosobenzene (cas 1423-13-8) with Os3(CO)12: synthesis and X-ray crystal structure of [Os3(CO)9(μ3-NC6F5)2]
Next:Reaction of pentafluoronitrosobenzene (cas 1423-13-8) with [Os3(CO)11(CH3CN)] and high-performance liquid chromatographic separation of [Os3(CO)11(μ-ONC6F5)], [Os3(CO)9(μ3-NC6F5)2], [Os3(CO)11(CH3CN)] and Os3(CO)12)