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14273-89-3

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14273-89-3 Usage

General Description

Methyl 6-chlorohexanoate is a synthetic organic compound that belongs to the class of esters. It is derived from the reaction of 6-chlorohexanoic acid with methanol. This chemical is commonly used in the fragrance and flavor industry, often serving as a key ingredient in various scents and perfumes. It is also used as a flavoring agent in food and beverage products due to its pleasant fruity and floral notes. Additionally, methyl 6-chlorohexanoate has potential applications in the pharmaceutical industry for its role as a building block in the synthesis of various drugs and pharmaceutical compounds. However, it is important to handle this chemical with care, as it may pose some health and safety risks if not properly managed.

Check Digit Verification of cas no

The CAS Registry Mumber 14273-89-3 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,4,2,7 and 3 respectively; the second part has 2 digits, 8 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 14273-89:
(7*1)+(6*4)+(5*2)+(4*7)+(3*3)+(2*8)+(1*9)=103
103 % 10 = 3
So 14273-89-3 is a valid CAS Registry Number.
InChI:InChI=1/C7H13ClO2/c1-10-7(9)5-3-2-4-6-8/h2-6H2,1H3

14273-89-3SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 17, 2017

Revision Date: Aug 17, 2017

1.Identification

1.1 GHS Product identifier

Product name methyl 6-chlorohexanoate

1.2 Other means of identification

Product number -
Other names 6-chloro-1-hexanoic acid methyl ester

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:14273-89-3 SDS

14273-89-3Relevant articles and documents

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Braunwarth,J.B.,Crosby,G.W.

, p. 2064 - 2067 (1962)

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Site-Selective Aliphatic C-H Chlorination Using N-Chloroamides Enables a Synthesis of Chlorolissoclimide

Quinn, Ryan K.,K?nst, Zef A.,Michalak, Sharon E.,Schmidt, Yvonne,Szklarski, Anne R.,Flores, Alex R.,Nam, Sangkil,Horne, David A.,Vanderwal, Christopher D.,Alexanian, Erik J.

supporting information, p. 696 - 702 (2016/02/03)

Methods for the practical, intermolecular functionalization of aliphatic C-H bonds remain a paramount goal of organic synthesis. Free radical alkane chlorination is an important industrial process for the production of small molecule chloroalkanes from simple hydrocarbons, yet applications to fine chemical synthesis are rare. Herein, we report a site-selective chlorination of aliphatic C-H bonds using readily available N-chloroamides and apply this transformation to a synthesis of chlorolissoclimide, a potently cytotoxic labdane diterpenoid. These reactions deliver alkyl chlorides in useful chemical yields with substrate as the limiting reagent. Notably, this approach tolerates substrate unsaturation that normally poses major challenges in chemoselective, aliphatic C-H functionalization. The sterically and electronically dictated site selectivities of the C-H chlorination are among the most selective alkane functionalizations known, providing a unique tool for chemical synthesis. The short synthesis of chlorolissoclimide features a high yielding, gram-scale radical C-H chlorination of sclareolide and a three-step/two-pot process for the introduction of the β-hydroxysuccinimide that is salient to all the lissoclimides and haterumaimides. Preliminary assays indicate that chlorolissoclimide and analogues are moderately active against aggressive melanoma and prostate cancer cell lines.

Iridium-catalyzed oxidative methyl esterification of primary alcohols and diols with methanol

Yamamoto, Nobuyuki,Obora, Yasushi,Ishii, Yasutaka

experimental part, p. 2937 - 2941 (2011/05/30)

Oxidative methyl esterification of primary alcohols and diols with methanol was successfully achieved, using acetone as a hydrogen acceptor, under the influence of an iridium complex combined with 2-(methylamino)ethanol (MAE) as catalyst.

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