1429410-85-4Relevant academic research and scientific papers
Arene CH-O hydrogen bonding: A stereocontrolling tool in palladium-catalyzed arylation and vinylation of ketones
Huang, Zhiyan,Lim, Li Hui,Chen, Zuliang,Li, Yongxin,Zhou, Feng,Su, Haibin,Zhou, Jianrong
, p. 4906 - 4911 (2013)
Weak is powerful: For the arylation of tin enolates, the palladium catalyst engages in weak CH-O hydrogen bonds to control stereoselectivity (see scheme). Similar catalysts capable of NH-O hydrogen bonding also works well. Copyright
Synthesis of γ-, δ-, and ε-lactams by asymmetric transfer hydrogenation of N-(tert-butylsulfinyl)iminoesters
Guijarro, David,Pablo, Oscar,Yus, Miguel
, p. 3647 - 3654 (2013/05/22)
Highly enantiomerically enriched γ- and δ-lactams have been prepared by a simple and very efficient procedure that involves the asymmetric transfer hydrogenation of N-(tert-butylsulfinyl)iminoesters followed by desulfinylation of the nitrogen atom and spo
