142945-18-4

Upstream product

• 70542-83-5 ethyl (2E)-5-(benzyloxy)pent-2-enoate 
• 105560-79-0 5-Benzyloxy-2-methylpentane-1,3-diol 
• 89923-31-9 (E)-5-(benzyloxy)pent-2-en-1-ol 
• 89956-14-9 [3-(2-Benzyloxyethyl)oxiran-2-yl]methanol 
• 19790-60-4 3-Benzyloxypropanal 
• 4799-68-2 3-benzyloxypropan-1-ol 
• 301230-09-1 5-Benzyloxy-1-(tert-butyldiphenylsilanyloxy)-2-methylpentane-3-ol 
• 74-88-4 methyl iodide 

Downstream Products

• 142954-43-6 5-(tert-Butyldiphenylsilanyloxy)-3-methoxy-4-methylpentanal 
• 166322-50-5 1-(tert-Butyldiphenylsilanyloxy)-3,7-dimethoxy-2,6-dimethyldec-9-en-5-ol 
• 166322-51-6 tert-Butyl(3,7-dimethoxy-5-methoxomethoxy-2,6-dimethyldec-9-enyloxy)diphenylsilane 
• 166322-47-0 3-(tert-Butyldimethylsilanyloxy)-7-(tert-butyldiphenylsilanyloxy)-5-methoxy-2,6-dimethylheptanal 
• 166322-49-2 6-(tert-Butyldimethylsilanyloxy)-10-(tert-butyldiphenylsilanyloxy)-4,8-dimethoxy-5,9-dimethyldec-1-ene 
• 301230-15-9 1-Benzyloxy-9-(tert-butyldiphenylsilanyloxy)-7-methoxy-4,8-dimethylnon-2-en-5-yl tert-butyldimethylsilyl ether 
• 166322-64-1 1-Benzyloxy-4-(tert-butyldimethylsilanyloxy)-10,14,16,16-tetramethoxy-12-methoxymethoxy-3,5,9,13-tetramethylhexadec-7-en-6-one 
• 203520-13-2 4-(tert-Butyldimethylsilanyloxy)-1-(tert-butyldiphenylsilanyloxy)-10,14,16,16-tetramethoxy-12-methoxymethoxy-3,5,9,13-tetramethylhexadec-6-one 
• 166322-48-1 6-(tert-Butyldimethylsilanyloxy)-10-(tert-butyldiphenylsilanyloxy)-8-methoxy-5,9-dimethyldec-1-en-4-ol 
• 203520-14-3 13-(tert-Butyldimethylsilanyloxy)-16-(tert-butyldiphenylsilanyloxy)-3,7-dimethoxy-5-methoxymethoxy-4,8,12,14-tetramethyl-11-oxohexadecanal 
• 203520-17-6 (E)-(3R,4R,5S,9S,10R,12R,13S,14R)-4-(tert-Butyl-dimethyl-silanyloxy)-1-(tert-butyl-diphenyl-silanyloxy)-17-(4-hydroxymethyl-[2,4';2',4'']teroxazol-2''-yl)-10,14-dimethoxy-12-methoxymethoxy-3,5,9,13-tetramethyl-heptadec-16-en-6-ol 
• 203520-15-4 2''-[(E)-(4R,5S,6R,8R,9S,13R,14R,15R)-14-(tert-Butyl-dimethyl-silanyloxy)-17-(tert-butyl-diphenyl-silanyloxy)-4,8-dimethoxy-6-methoxymethoxy-5,9,13,15-tetramethyl-12-oxo-heptadec-1-enyl]-[2,4';2',4'']teroxazole-4-carboxylic acid methyl ester 
• 166322-52-7 9-(tert-Butyldiphenylsilanyloxy)-3,7-dimethoxy-5-methoxomethoxy-4,8-dimethylnonanal 
• 301230-14-8 1-Benzyloxy-9-(tert-butyldiphenylsilanyloxy)-7-methoxy-4,8-dimethylnon-2-en-5-ol 

Relevant academic research and scientific papers

Synthetic Studies towards Halichondramides, and Related Novel tris-Oxazole Containing Macrolides from Marine Organisms. A Concise Route to the Keto-triol Formyl Enamine Moiety.

A synthesis of the keto-triol formyl enamine moiety (3) in the marine metabolite halichondramide (1) is described.The synthesis features judicious application of the Evans chiral aldol protocol in combination with the controlled ring opening of chiral α-e

A total synthesis of the unique tris-oxazole macrolide ulapualide a produced by the marine nudibranch Hexabranchus sanguineus

A total synthesis of ulapualide A (1), whose relative stereochemistry was assigned on the basis of an earlier molecular mechanics study of its hypothetical metal chelated complex 9, is described. The synthesis is based on: i, elaboration of the double fun