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1429939-35-4

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  • 1,1'-[(5aS,8aS,14aS)-5a,6,7,8,8a,9-Hexahydro-5H-[1]benzopyrano[3,2-d]xanthene-1,13-diyl]bis[1,1-bis(3,5-dimethylphenyl)phosphine

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  • (+)-1,13-Bis[di(3,5-diMethylphenyl)phosphino]-(5aR,8aR,14aR)-5a,6,7,8,8a,9-hexahydro-5H-[1]benzopyrano[3,2-d]xanthene, 97% (R,R,R)-(+)-Xyl-SKP

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  • (+)-1,13-Bis[di(3,5-dimethylphenyl)phosphino]-(5aR,8aR,14aR)-5a,6,7,8,8a,9-hexahydro-5H-[1]benzopyrano[3,2-d]xanthene, 97% (R,R,R)-(+)-Xyl-SKP

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1429939-35-4 Usage

Reaction

Efficient ligand for the palladium-catalyzed, asymmetric allylic amination of racemic Morita-Baylis-Hillman adducts.

Check Digit Verification of cas no

The CAS Registry Mumber 1429939-35-4 includes 10 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 7 digits, 1,4,2,9,9,3 and 9 respectively; the second part has 2 digits, 3 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 1429939-35:
(9*1)+(8*4)+(7*2)+(6*9)+(5*9)+(4*3)+(3*9)+(2*3)+(1*5)=204
204 % 10 = 4
So 1429939-35-4 is a valid CAS Registry Number.

1429939-35-4Downstream Products

1429939-35-4Relevant articles and documents

A chiral α - methylene β - lactam compound and its preparation method and application

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Paragraph 0397; 0401-0403, (2017/12/28)

Disclosed are a chiral alpha-methylene-beta-lactam compound and a preparation method and an application thereof. An asymmetric allyl amination reaction of catalyzing a class of Morita-Baylis-Hillman adducts by using a complex formed by a chiral phosphine

PROCESS FOR SYNTHESIS OF EZETIMIBE AND INTERMEDIATES USED IN SAID PROCESS

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Paragraph 0222; 0223; 0227; 0228, (2015/06/24)

A process for the production of ezetimibe and intermediates used in said process are disclosed. A kind of Morita-Baylis-Hillman adduct can be altered to chiral carboxylic acid derivatives of β-arylamino α-methylene with high activity and selectivity by means of ally lamination reaction, and the above carboxylic acid derivatives of β-arylamino α-methylene can be altered to the chiral intermediates of ezetimibe by means of simple conversion and further synthesized into the chiral drug ezetimibe. The synthesis route introduces chirality through the use of a chiral catalysis method, thereby avoiding the use of the chiral auxiliary oxazolidinone; and the route is economical and eco-friendly.

Practical asymmetric catalytic synthesis of spiroketals and chiral diphosphine ligands

Wang, Xiaoming,Wang, Xubin,Guo, Peihua,Wang, Zheng,Ding, Kuiling

supporting information, p. 2900 - 2907 (2014/03/21)

A practical procedure has been developed for efficient synthesis of chiral aromatic spiroketals and the relevant diphosphine ligands. The procedure includes first asymmetric hydrogenation of readily available α, α'-bis(2-benzyloxyarylidene) ketones cat-al

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