14311-22-9

Upstream product

• 4551-15-9 phenylthiotrimethylsilane 
• 1138-99-4 diphenyltrifluorophosphorane 
• 20057-88-9 diphenyl trisulfide 
• 58558-57-9 (4-methylphenylthio)diphenylphosphan 
• 108-98-5 thiophenol 
• 1079-66-9 chloro-diphenylphosphine 
• 1636-15-3 (diethylamino)diphenylphosphine 
• 97135-49-4 bis(diisopropylamino)phosphanylnitrile 
• 829-85-6 diphenylphosphane 

Downstream Products

• 84589-82-2 diphenylphosphine hydrogen iodide 
• 108-98-5 thiophenol 
• 20472-52-0 iodo-diphenyl-phosphine 
• 3878-45-3 triphenylphosphine sulfide 
• 2751-90-8 tetraphenylphosphonium bromide 
• 791-28-6 Triphenylphosphine oxide 
• 6591-07-7 diphenylphosphane sulfide 
• 5271-36-3 P,P-diethyldibenzophospholium iodide 
• 829-85-6 diphenylphosphane 
• 12150-46-8 1,1'-bis-(diphenylphosphino)ferrocene 
• 216434-36-5 Co₂(CO)5(HCCCH₂OH)((C₆H₅)2PSC₆H₅) 
• 216434-53-6 Co₂(CO)4(HCCCH₂OH)((C₆H₅)2PSC₆H₅)2 

Relevant academic research and scientific papers

Selective homo- and heterodehydrocouplings of phosphines catalyzed by rhodium phosphido complexes

Reactions of the rhodium complex (dippe)Rh(η3-CH2Ph) (1, dippe = iPr2PCH2CH2PiPr2) with ArPH2 (Ar = Ph, Mes) proceed via P-H oxidative additions to the phosphido complexes (dippe)Rh(μ-PHAr)2Rh(dippe) (3a, Ar = Ph; 3b, Ar = Mes). The corresponding reaction of Ph2PH occurs similarly, via the intermediate (dippe)Rh(PPh2)PHPh2 (4), to (dippe)Rh(μ-PPh2)2Rh(dippe) (3c). Complexes 3a-c and 4 are catalysts for the catalytic dehydrodimerizations of the corresponding phosphines to diphosphanes. Complex 1 is a more active dehydrocoupling catalyst, and substituent effects suggest that the active catalyst is mononuclear. Efficient dehydrocouplings of 2-EtC6H4PH2, 2-iPrC6H4PH2, and 2,4,6-iPr3C6H2PH2 were also observed. Complex 1 also catalyzes the heterocoupling of Ph2PH with PhSH (to Ph2P-SPh), and stoichiometric reactions in this system allowed isolation of (dippe)Rh(μ-SPh)2Rh(dippe) (6) and (dippe)Rh(SPh)PHR2 (7a, R2PH = MesPH2; 7b, R2PH = Ph2PH). Copyright

X-H (X = C, N, O, P, S) Bond Activations Induced by β-Heterosubstituted Zirconaindenes

The azazirconacyclopentene-substituted phosphines 3 and 4 have been found to activate the C-H bonds of acetylenic systems, such as methylpropiolate, diphenylphosphinoacetylene and phenylacetylene, or of methylene compounds, such as malonitrile and diethyl

The Kinetics and Mechanism of the Reaction of Tricoordinate Phosphorus Compounds with Diaryl Trisulfides

Kinetic data and activation parameters are reported for the reaction of a series of tricoordinate phosphorus compounds, , with diaryl trisulfides.The second-order rate coefficients for series of arylphosphines, phosphinites and phosphonites, correlate with the Hammett ? constants of the aryl substituents with ρ values of -1.1, -1.1 and -1.1 respectively and these results are discussed in terms of a biphilic mechanism analogous to that proposed for the reaction of tricoordinate phosphorus with S8.

PHOSPHORORGANISCHE VERBINDUNGEN 93 Zur Chemie optisch aktiver Phosphinigsaereamide

Optically active ethyl-phenyl-phosphinous acid diethylamide 1 was treated with HCl, HBF4, alcohols, thiols, carboxylic acids, esters, anhydrides, acid chloride, compounds with the structure element P-Cl and secondary phosphines to give in each case a racemic mixture of the corresponding, previously described, reaction products.Reaction of optically active 1 with para-cresol, para-cresyltrifluoro-acetate or 2,2,2-trifluoro-ethyl-trifluoro-acetate gives the corresponding optically active ester of ethyl phenyl phosphinous acid under retention of configuration.

PHOSPHORORGANISCHE VERBINDUNGEN 90 Methodische Ausgestaltung der P-C und P-S-Cyanolyse am Beispiel einiger Heterophosphoniumsalze

Treatment of allylamido-phosphonium salts with dry tetrabutylammonium cyanide in methylenechloride delivers after removal of the allyl group phosphinous acid amides with retention of configuration (P-C-cyanolysis).Allyl-O-alkylphosphonium salts undergo the Arbosov reaction under the above conditions, while allyl-S-alkyl phosphonium salts undergo fission of the P-S bond (P-S cyanolysis).Equally good results were obtained using KCN in methylene chloride accompained by catalytic amounts of 18-crown-6 ether; thus optically active benzyl-methyl-phenyl-phosphine-sulfid gave the corresponding phosphine with retention of configuration.Dithiophosphinic acid esters and thiophosphinic acid amides, after conversion to the corresponding quasiphosphonium salts via S-alkylation and subsequent treatment with tetrabutylammonium cyanide in methylenechloride, also give the corresponding thiophosphinous acid ester and phosphinous acid amide respectively.Thiophosphinic acid O-alkyl esters (R2P(S)OR') give however the thiophosphinic S-alkyl ester (R2P(O)SR') via an Arbusov reaction.The P-C cyanolysis of allyl-triphenylphosphoniumbromide using KCN/18-crown-6 or tetrabutylammonium cyanide in aprotic medium stops at the stage of the intermediary red-coloured ylide; addition of a proton-donor then results in the subsequent rearrangement to the corresponding propenyl-phosphonium salt.