143359-33-5

Upstream product

• 130514-05-5 (R)-2-((R)-Benzenesulfinyl)-3-phenyl-propan-1-ol 
• 100-39-0 benzyl bromide 
• 123299-91-2 (R)-2-(phenylsulfinyl)ethanol 
• 143359-24-4 (4R,5S)-1,5-Dimethyl-4-phenyl-3-(2-phenylsulfanyl-acetyl)-imidazolidin-2-one 
• 930-69-8 sodium thiophenolate 
• 143359-41-5 (4S,5R)-1,5-Dimethyl-4-phenyl-3-((R)-3-phenyl-2-phenylsulfanyl-propionyl)-imidazolidin-2-one 
• 54532-94-4 ethyl α-phenylmercapto-phenylpropionate 

Downstream Products

• 20780-53-4 (R)-Styrene oxide 
• 16158-83-1 1-methyl-2-phenylethenyl phenyl sulfide 

Relevant academic research and scientific papers

A new approach to 2-phenylthioalcohols in high optical purity

2-Phenylthioalcohols are prepared in high optical purity by alkylation of chiral imides of 2-phenylthioacetic acid, obtained starting from chiral imidazolidin-2-ones.

ALKYLATION OF 2-PHENYLSULFINYLETHANOL

Alkylation of 2-phenylsulfinylethanol resulted syndiastereomer as the major products, although the ratio of syn/anti isomers varied depending on the alkyl group.By application of this prodeure to the chiral sulfoxides, optically active epoxides have been obtained in good yields.