16158-83-1

Basic information

• Product Name: Benzene, [(1-methyl-2-phenylethenyl)thio]-
• CAS NO: 16158-83-1
• Molecular Formula: C15H14S
• Molecular Weight: 226.342
• Mol File: 16158-83-1.mol
• Article Data: 24

Chemical Properties

• CAS DataBase Reference: Benzene, [(1-methyl-2-phenylethenyl)thio]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [(1-methyl-2-phenylethenyl)thio]-(16158-83-1)
• EPA Substance Registry System: Benzene, [(1-methyl-2-phenylethenyl)thio]-(16158-83-1)

Safety Data

• Hazardous Substances Data: 16158-83-1(Hazardous Substances Data)

Upstream product

• 28911-66-2 N-methyl-N-(phenylthio)acetamide 
• 1530-32-1 ethyltriphenylphosphonium bromide 
• 100-52-7 benzaldehyde 
• 2327-99-3 1-phenylpropadiene 
• 108-98-5 thiophenol 
• 10147-11-2 propargyl benzene 
• 38066-16-9 diethyl [(phenylthio)methyl]phosphonate 
• 74-88-4 methyl iodide 
• 673-32-5 1-Phenylprop-1-yne 
• 882-33-7 diphenyldisulfane 
• 137-06-4 2-thiocresol 
• 16158-83-1 (Z)-β-phenylthio-β-methylstyrene 
• 36306-33-9 [2,2-di(phenylsulfanyl)propyl]benzene 
• 13307-56-7 1,1-bis(phenylthio)ethane 

Downstream Products

• 16158-83-1 phenyl (1E)-1-phenylprop-1-en-2-yl sulfide 
• 103-79-7 1-phenyl-acetone 
• 103-65-1 phenylpropane 

Relevant articles and documents

Radical Polymerization Behavior of Phenylallene. Synthesis of Functional Polymer Containing Styryl Moiety on the Backbone

Radical homopolymerization of phenylallene (PA) and copolymerization of PA with some vinyl monomers were described.PA polymerized selectively by the terminal double bond of allene both in the homopolymerization and the copolymeriation.The radical reaction

Highly stereoselective anti-Markovnikov hydrothiolation of alkynes and electron-deficient alkenes by a supported Cu-NHC complex

A practical, efficient, and low-cost heterogeneous catalyst consisting of a Cu-NHC (N-heterocyclic carbene) complex grafted to SBA-15 silica for the catalytic hydrothiolation of alkynes and electron-deficient alkenes under mild reaction conditions has been developed. The heterogeneous catalyst displays higher activity and stereoselectivity to Z-anti-Markovnikov isomers compared with the homogeneous analog under otherwise identical reaction conditions. The catalytic system is applicable to a broad range of alkynes and thiols and is recyclable without significant loss in catalytic performance. High activity and perfect selectivity to alkyl sulfides formed by the addition of electron-deficient alkenes to various thiols catalyzed by the supported Cu-NHC complex were also realized. This journal is the Partner Organisations 2014.

Alkyne hydrothiolation catalyzed by a dichlorobis(aminophosphine) complex of palladium: Selective formation of cis-configured vinyl thioethers

Cis all round: Dichlorobis[1-(dicyclohexylphosphanyl)piperidine]palladium, [(P{(NC5H10)(C6H11) 2})2Pd(Cl)2], is a highly efficient alkyne hydrothiolation catalyst and the first generally applicable system that selectively generates cis-configured anti-Markovnikov adducts in excellent yields within only a few minutes at 120 °C in the presence of only 0.05 mol % of the catalyst (see scheme).