143366-20-5

Basic information

• Product Name: Benzoic acid, 2-[3,3,4,4,5,5,5-heptafluoro-2-(2-methoxy-2-oxoethylidene)-1-(triphenyl phosphoranylidene)pentyl]-, ethyl ester, (Z)-
• CAS NO: 143366-20-5
• Molecular Formula: C35H28F7O4P
• Molecular Weight: 676.568
• Mol File: 143366-20-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzoic acid, 2-[3,3,4,4,5,5,5-heptafluoro-2-(2-methoxy-2-oxoethylidene)-1-(triphenyl phosphoranylidene)pentyl]-, ethyl ester, (Z)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzoic acid, 2-[3,3,4,4,5,5,5-heptafluoro-2-(2-methoxy-2-oxoethylidene)-1-(triphenyl phosphoranylidene)pentyl]-, ethyl ester, (Z)-(143366-20-5)
• EPA Substance Registry System: Benzoic acid, 2-[3,3,4,4,5,5,5-heptafluoro-2-(2-methoxy-2-oxoethylidene)-1-(triphenyl phosphoranylidene)pentyl]-, ethyl ester, (Z)-(143366-20-5)

Safety Data

• Hazardous Substances Data: 143366-20-5(Hazardous Substances Data)

Upstream product

• 7115-91-5 2-ethoxycarbonylbenzyl bromide 
• 603-35-0 triphenylphosphine 
• 59636-00-9 (o-ethoxycarbonylbenzyl)triphenylphosphonium bromide 
• 70577-96-7 methyl 4,4,5,5,6,6,6-heptafluorohex-2-ynoate 

Relevant articles and documents

A convenient synthesis of methyl 1-alkoxy-3-perfluoroalkyl-2-naphthoates

Methyl 1-alkoxy-3-perfluoroalkyl-2-naphthoates 5 were synthesized by heating appropriately substituted 2-triphenylphosphoranylidene-2-butenoates 3 in xylenes at 250°C in a sealed tube. Compounds 3 were obtained via an intramolecular Wittig reaction of 2-alkoxycarbonylbenzyltriphenylphosphonium bromide (1) with methyl 2-perfluoroalkynoates 2 in the presence of potassium carbonate.