143774-66-7Relevant academic research and scientific papers
Cu(OTf)2 catalysed [6+2] cycloaddition reaction for the synthesis of highly substituted pyrrolo[1,2-a]indoles: Rapid construction of the yuremamine core
Dethe, Dattatraya H.,Boda, Raghavender,Das, Saikat
supporting information, p. 3260 - 3262 (2013/04/24)
Lewis acid catalysed [6+2] cycloaddition reaction for the synthesis of pyrrolo[1,2-a]indoles generating three contiguous stereocenters in a highly regio- and diastereoselective manner has been developed and further applied for the construction of the fully functionalized tricyclic core of yuremamine.
A direct lithiation route to 2-acyl-1-(phenylsulfonyl)indoles
Jiang, Jun,Gribble, Gordon W.
, p. 2035 - 2040 (2007/10/03)
2-Acyl-1-(phenylsulfonyl)indoles (3, 7-9) are prepared in 75-84% yield from 1-(phenylsulfonyl)indoles (1, 5) in one operation by treatment of the latter with s-butyllithium followed by inverse quenching of the C-2 lithioindoles with carboxylic acid anhydr
Magnesiation of indoles with magnesium amide bases
Kondo, Yoshinori,Yoshida, Akihiro,Sakamoto, Takao
, p. 2331 - 2332 (2007/10/03)
1-Substituted indole derivatives are deprotonated with Hauser bases (R2NMgBr) or magnesium diamide [(R2N)2-Mg] to give magnesioindoles which are then reacted with electrophiles.
