143885-02-3

Basic information

• Product Name: propyloxy(diphenyl)-λ⁶-sulfanenitrile
• Synonyms: propyloxy(diphenyl)-λ⁶-sulfanenitrile
• CAS NO: 143885-02-3
• Molecular Weight: 259.372
• Mol File: 143885-02-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: propyloxy(diphenyl)-λ⁶-sulfanenitrile(CAS DataBase Reference)
• NIST Chemistry Reference: propyloxy(diphenyl)-λ⁶-sulfanenitrile(143885-02-3)
• EPA Substance Registry System: propyloxy(diphenyl)-λ⁶-sulfanenitrile(143885-02-3)

Safety Data

• Hazardous Substances Data: 143885-02-3(Hazardous Substances Data)

Upstream product

• 71-23-8 propan-1-ol 
• 42787-33-7 S,S-Diphenyl-N-chlorosulfilimine 
• 67248-39-9 fluoro(diphenyl)-λ⁶-sulfanenitrile 
• 6819-41-6 sodium n-propoxide 
• 42787-34-8 S,S-Diphenyl-N_.bromosulfilimine 

Downstream Products

• 4712-36-1 O-Deutero-n-propanol 
• 22731-83-5 S,S-diphenylsulphoximine 
• 5470-02-0 N-propylpiperidine 
• 599-91-7 propyl tosylate 
• 874-79-3 phenyl(propyl)sulfide 
• 55245-43-7 N-(4-chlorobenzyl)propan-1-amine 
• 540-54-5 1-Chloropropane 
• 622-85-5 propoxybenzene 
• 383-66-4 1-(trifluoroacetoxy)propane 
• 109-60-4 1-Propyl acetate 
• 36744-90-8 S,S-Diphenylsulfilimine 
• 123-38-6 propionaldehyde 
• 139-66-2 diphenyl sulfide 

Relevant articles and documents

Synthesis, Structure, and Thermolysis Mechanism of S-Alkoxythiazynes

S-Alkoxy-S,S-diarylthiazynes were prepared by two methods: the alkaline hydrolysis of S,S-diaryl-N-halosulfilimines in aqueous alcohols and the reaction of S,S-diaryl-S-fluorothiazynes with sodium alkoxides. The structure of S,S-diphenyl-S-propoxythiazyne was determined by an X-ray crystallographic analysis, which showed a short SN bond length of 1.441(3) A. The thermolysis of S-alkoxythiazynes gave elimination products, which were identified as the corresponding carbonyl compounds and N-unsubstituted S,S-diarylsulfilimines. Kinetic experiments for the thermolysis of the S-alkoxy-S,S-diarylthiazynes were carried out. The first-order kinetic behavior, a large kinetic isotope effect (kHkD = 6.1 ) using S,S-diphenyl-S-[1,1-2H2]propoxythiazyne, a negative activation entropy (ΔS? = -30 J K-1mol-1), and a negative Hammett ρ-value (ρ= -0.35) on the phenyl group were obtained, suggesting that the reaction proceeds via a concerted five-membered cyclic transition state. A deviation from the ideal concerted transition state is discussed in comparison with that for sulfoxides.