143949-38-6Relevant articles and documents
Preparation of alkyl-substituted indoles in the benzene portion. Part 11. Total synthesis of (6R,8S)-herbindole A, (6R,8S)-herbindole B, (6R,8S)-herbindole C (6R,8S)-cis-trikentrin A, (6R,8S)-cis-trikentrin B, (6R,8R)-trans-trikentrin B, and (6R,8R)-iso-t
Muratake,Mikawa,Seino,Natsume
, p. 854 - 864 (1994)
The key intermediate, (3R,5S)-3,5-dimethyl-1-cyclopentenylmethanol (13) for chiral syntheses of herbindoles and trikentrins, was prepared from the known Diels-Alder adduct 12. Employing pertinent methodologies developed in the previous model study (preced
Total synthesis of (+)-herbindole A, (+)-herbindole B, and (+)-herbindole C. Determination of the absolute configuration of the natural herbindoles
Muratake,Mikawa,Natsume
, p. 4595 - 4598 (2007/10/02)
(6R, 8S)-(+)-Herbindoles A (3a), B (3b), and C (3c) were synthesized from the chirality-definite Diels-Alder adduct 7 using an acid-induced indole cyclization reaction of 4 to 5, as well as novel reactions of the PhSO2 group of 24 with Mg in Me