14396-29-3Relevant articles and documents
Application of Thermal Kinetics to Small Carbon Ion Clusters
Lifshitz, Chava,Sandler, Pablo,Gruetzmacher, Hans-Friedrich,Sun, Jing,Weiske, Thomas,Schwarz, Helmut
, p. 6592 - 6597 (1993)
Kinetic energy release distributions (KERDs) were obtained experimentally for unimolecular decomposition of small carbon ion clusters Cn+, n = 10-13 and 18, made by dissociative ionization from perchloro conjugated hydrocarbons.A model-free approach due to Klots, based on the application of thermal kinetics to small systems, allowed the extraction of binding energies for these clusters.The results were found to be in very good agreement with literature values for collisionally activated dissociation (CAD) threshold energies.The ion C11+ demonstrates a particularly high binding energy in agreement with its magic character in Cn+ mass spectra, while C13+ has a relatively low binding energy, reflected in its low abundance in such spectra.
Extensive Chlorination of Methylnaphthalenes, Friedel-Crafts Alkylation of Pentachlorobenzene by Heptachloro(chloromethyl)naphthalenes, and Related Results
Garcia, R.,Riera, J.,Carilla, J.,Julia, L.,Molins, E.,Miravitlles, C.
, p. 5712 - 5719 (2007/10/02)
The chlorination of 2-methylnaphthalene (1) and 1-methylnaphthalene (12) by means of Silberrad's reagent (initial components: SO2Cl2, S2Cl2, and AlCl3) has been performed.From 1 or 12, the following compounds have been synthesized for first time: nonachlo