143994-75-6Relevant academic research and scientific papers
Facile Synthesis of Thiolariat Ethers or Crown Ethers Containing a Mercapto Group as a Side Arm
Nabeshima, Tatsuya,Tsukada, Naoko,Haruyama, Tsutomu,Yano, Yumihiko
, p. 227 - 229 (2007/10/02)
Cyclization reaction of S-substituted thioglycerol and oligoethylene glycol ditosylate gave thiolariat ethers in moderate yields.Mercaptomethyl crown ethers were obtained easily from benzylthiomethyl crown ethers by Na in liq.NH3-BuOH.
Remarkably Selective Binding of Silver Ion by Thiolariat Ether with a 15-Cown-5 Ring
Nabeshima, Tatsuya,Nishijima, Katsunori,Tsukada, Naoko,Furusawa, Hiroyuki,Hosoya, Toshiyuki,Yano, Yumihiko
, p. 1092 - 1094 (2007/10/02)
The thiolariat ether, which is a lariat ether with an oxygen atom in the side arm replaced by a sulfur atom, exhibits a high selectivity to silver ion among alkali and heavy metal ions because of synergistic ligation of the crown ether and the one sulfur
