144-54-7Relevant articles and documents
Method for synthesizing metham in one step
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Paragraph 0021-0022; 0024, (2020/11/12)
The invention discloses a method for synthesizing a soil fumigant metham in one step. The method comprises the following steps: stirring and mixing water, a monomethylamine aqueous solution and a sodium hydroxide aqueous solution, dropwise adding carbon disulfide, continuously stirring and reacting to obtain a finished product of metham with the appearance of yellow to red brown, wherein the finished product is used for treating soil fumigation and disinfection and killing root-knot nematodes, harmful bacteria and soil insects and removing weeds. The whole synthesis method has the advantages of high production efficiency, high product content, high operation safety, good storage stability and environmental friendliness.
Dazomet preparation process
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Paragraph 0022; 0023; 0024; 0025; 0037; 0038; 0039-0049, (2017/07/19)
The invention discloses a dazomet preparation process. The process comprises the following steps: of the first step reaction: enabling methylamine to react with carbon disulfide, adding an appropriate amount of extracting agent, separating to obtain an intermediate N-methylaminodithioformate; the second step reaction: enabling the intermediate N-methylaminodithioformate to react with formaldehyde in a reaction system added with an appropriate amount of sulfate and surfactant to obtain the dazomet. By use of the scheme disclosed by the invention, the extracting agent is added after the first step reaction is finished; the product carbon disulfide is further removed, thereby avoiding the influence on the product crystal structure, packing density and production security by residual carbon disulfide.
Synthesis of new hyodeoxycholic acid thiosemicarbazone derivatives under solvent-free conditions using microwave
Shi, Zhi Chuan,Zhao, Zhi Gang,Liu, Xing Li,Chen, Yu
experimental part, p. 405 - 408 (2012/01/05)
An efficient and simple method for synthesis of new hyodeoxycholic acid thiosemicarbazone derivatives under solvent-free conditions using microwave has been developed. Its main advantages are short reaction times, good conversions and the environmentally friendly nature of the process. The preliminary results indicate that some of these compounds possess inhibitory effects against E. coli.