Bulletin of the Chemical Society of Japan p. 1263 - 1268 (1995)
Update date:2022-09-26
Topics:
Yanagisawa, Akira
Hibino, Hiroaki
Habaue, Shigeki
Hisada, Yoshiyuki
Yasue, Katsutaka
Yamamoto, Hisashi
The highly α,α' selective and sterocontrolled homocoupling reaction of allylic halides was achieved using barium reagent.The double-bond geometry of the starting allylic chloride was completely retained.The α,α' cross-coupling products were also prepared stereospecifically and regioselectively by this method.
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