1441-57-2

Basic information

• Product Name: 1,4-Bis(ethoxycarbonyl)-1,3-butadiene
• Synonyms: 1,4-Bis(ethoxycarbonyl)-1,3-butadiene;2,4-Hexadienedioic acid diethyl ester;Diethyl muconate;Muconic acid diethyl
• CAS NO: 1441-57-2
• Molecular Formula: C₁₀H₁₄O₄
• Molecular Weight: 198.22
• Mol File: 1441-57-2.mol
• Article Data: 4

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 1,4-Bis(ethoxycarbonyl)-1,3-butadiene(CAS DataBase Reference)
• NIST Chemistry Reference: 1,4-Bis(ethoxycarbonyl)-1,3-butadiene(1441-57-2)
• EPA Substance Registry System: 1,4-Bis(ethoxycarbonyl)-1,3-butadiene(1441-57-2)

Safety Data

• Hazardous Substances Data: 1441-57-2(Hazardous Substances Data)

Usage

Chemical structure

A butadiene backbone with two ethoxycarbonyl groups attached to separate carbon atoms

Type of compound

Diene derivative

Applications

a. Building block in organic synthesis
b. Creation of various polymers and materials
c. Production of specialty chemicals and pharmaceuticals
d. Materials science and engineering applications

Reactivity

Known for its reactivity in Diels-Alder reactions

Potential

Ability to form cross-linked polymers

Upstream product

• 64-17-5 ethanol 
• 3588-17-8 (2E,4E)-2,4-hexadienedioic acid 
• 261900-70-3 D-glucarate-6,3-lactone ethyl ester 
• 45214-05-9 diethyl glucarate 
• 55531-67-4 ethyl 4,4-diethoxy-2-butenoate 
• 5654-07-9 1,1-bis(trimethylsilyl)ethylene 
• 31930-36-6 ethyl (Z)-3-iodopropenoate 
• 107-21-1 ethylene glycol 
• 1099-45-2 ethyl (triphenylphosphoranylidene)acetate 
• 75-50-3 trimethylamine 
• 91-66-7 N,N-diethylaniline 
• 867-13-0 diethoxyphosphoryl-acetic acid ethyl ester 
• 2960-66-9 ethyl 4-oxo-2-butenoate 

Downstream Products

• 64367-55-1 Fe(CO)(C₂H₅O₂CCHCHCHCHCO₂C₂H₅)(C₅H₄NC(C₆H₅)NC₆H₅) 

Relevant articles and documents

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A new selective approach to 1,1-bis(silyl)-2-arylethenes and 1,1-bis(silyl)-1,3-butadienes via sequential silylative coupling-heck coupling reactions

A novel selective route to 1,1-bis(silyl)-1-alkenes has been developed. Sequential one-pot silylative coupling exo-cyclization of 1,2- bis(dimethylvinylsiloxy)ethane followed by the reaction with Grignard reagents leads to the desired 1,1-bis(silyl)ethene

DISSYMETRATION DE LA MOLECULE DU GLYOXAL 1-SYNTHESE ET REACTIVITE DE L'ACETOXY-1 TRIETHOXY-1,2,2 ETHANE

Acetoxy-1 triethoxy-1,2,2 ethane, a dissymetric derivative of glyoxal, is prepared and reacted with various bases and nucleophiles, as amines, cyanotrimethylsilane, organometallic and WITTIG reagents.Various acetals are obtained, leading to α-fonctionalized aldehydes.