1441-57-2

Usage

Chemical structure

A butadiene backbone with two ethoxycarbonyl groups attached to separate carbon atoms

Type of compound

Diene derivative

Applications

a. Building block in organic synthesis
b. Creation of various polymers and materials
c. Production of specialty chemicals and pharmaceuticals
d. Materials science and engineering applications

Reactivity

Known for its reactivity in Diels-Alder reactions

Potential

Ability to form cross-linked polymers

Upstream product

• 64-17-5 ethanol 
• 261900-70-3 D-glucarate-6,3-lactone ethyl ester 
• 45214-05-9 diethyl glucarate 
• 5654-07-9 1,1-bis(trimethylsilyl)ethylene 
• 31930-36-6 ethyl (Z)-3-iodopropenoate 
• 75-50-3 trimethylamine 
• 91-66-7 N,N-diethylaniline 
• 867-13-0 diethoxyphosphoryl-acetic acid ethyl ester 
• 2960-66-9 ethyl 4-oxo-2-butenoate 
• 3588-17-8 (2E,4E)-2,4-hexadienedioic acid 
• 55531-67-4 ethyl 4,4-diethoxy-2-butenoate 
• 107-21-1 ethylene glycol 
• 1099-45-2 ethyl (triphenylphosphoranylidene)acetate 

Downstream Products

• 64367-55-1 Fe(CO)(C₂H₅O₂CCHCHCHCHCO₂C₂H₅)(C₅H₄NC(C₆H₅)NC₆H₅) 

Relevant academic research and scientific papers

DEOXYDEHYDRATION OF SUGAR DERIVATIVES

The disclosure provides methods for deoxydehydration of sugar-based derivatives using hydrogen gas as a reducing agent.

A new selective approach to 1,1-bis(silyl)-2-arylethenes and 1,1-bis(silyl)-1,3-butadienes via sequential silylative coupling-heck coupling reactions

A novel selective route to 1,1-bis(silyl)-1-alkenes has been developed. Sequential one-pot silylative coupling exo-cyclization of 1,2- bis(dimethylvinylsiloxy)ethane followed by the reaction with Grignard reagents leads to the desired 1,1-bis(silyl)ethene

Desymmetrization of diols by a tandem oxidation/Wittig olefination reaction

Diols are desymmetrized by a tandem oxidation/Wittig olefination to give α,β-unsaturated hydroxy esters without the requirement for protecting group strategies; the α,β-unsaturated hydroxy esters are transformed into dienyl diesters using a second oxidation/Wittig olefination sequence using PCC. The Royal Society of Chemistry 2006.

DISSYMETRATION DE LA MOLECULE DU GLYOXAL 1-SYNTHESE ET REACTIVITE DE L'ACETOXY-1 TRIETHOXY-1,2,2 ETHANE

Acetoxy-1 triethoxy-1,2,2 ethane, a dissymetric derivative of glyoxal, is prepared and reacted with various bases and nucleophiles, as amines, cyanotrimethylsilane, organometallic and WITTIG reagents.Various acetals are obtained, leading to α-fonctionalized aldehydes.