144261-77-8Relevant academic research and scientific papers
Experimental and Theoretical Study on the Olefin Metathesis of Alkenyl Baylis-Hillman Adducts Using Second-Generation Grubbs Catalyst
Lee, Mi Jung,Lee, Ka Young,Lee, Jin Yong,Kim, Jae Nyoung
, p. 3313 - 3316 (2007/10/03)
We have investigated the olefin metathesis from alkenyl Baylis-Hillman adducts using second-generation Grubbs catalyst. In the experiment, the ring-closing metathesis (RCM) product could be found, while the cross-metathesis (CM) products were f
The 'Baylis - Hillman reaction' mechanism and applications revisited
Fort, Yves,Berthe, Marie Christine,Caubere, Paul
, p. 6371 - 6384 (2007/10/02)
It is shown that reaction of aryl, benzyl, alkyl and functionalised alkyl acrylic esters with benzaldehyde, in the presence of 1,4-diazabicyclo[2.2.2] octane, strongly depends upon the electronic and steric effects of the ester part. This influence is also observed in condensation of furfuraldehyde. Moreover, for the first time, it is shown that the overall condensation is equilibrated.
