76200-37-8Relevant academic research and scientific papers
Strategic Trimethylsilyldiazomethane Insertion into pinB-SR Followed by Selective Alkylations
Civit, Marc G.,Royes, Jordi,Vogels, Christopher M.,Westcott, Stephen A.,Cuenca, Ana B.,Fernández, Elena
, p. 3830 - 3833 (2016/08/16)
The insertion of the diazo derivative Me3SiCHN2 into pinB-SR σ bonds (R = Ph, Tol, Bn) allows a direct synthesis of multisubstituted H-C(SR)(Bpin)(SiMe3) compounds. Consecutive base-assisted transformations of HC(S)(B) (Si
Synthesis of Aldehydes from Phenylthiotrimethylsilylmethane
Ager, David J.
, p. 1131 - 1136 (2007/10/02)
Phenylthiotrimethylsilylmethyl-lithium (4) reacts with alkyl halides to give 1-phenylthio-1-trimethylsilylalkanes (5), which can also be prepared by the addition of alkyl-lithium to 1-phenylthio-1-trimethylsilylethene (8), or from bis(phenylthio)acetals (11).The 1-phenylthio-1-trimethylsilylalkanes (5) can be converted into the corresponding aldehyde (15) by oxidation to the sulphoxide (13), thermal rearrangement, and hydrolysis of the resultant O-silyl thioacetal (14).
A NEW METHOD FOR PREPARING 1-PHENYLTHIO-1-TRIMETHYLSILYLALKANES: THE PREPARATION OF α-SILYLCARBANIONS AND OLEFINS.
Ager, David J.
, p. 2923 - 2926 (2007/10/02)
1-Phenylthio-1-trimethylsilylalkanes(1) are prepared in high yield from 1,1-bis(phenylthio)acetals(2) by reaction with lithium naphthalenide(3) followed by chlorotrimethylsilane. α-Silylcarbanions are formed from the alkanes(1) and lithium naphthalenide(3).Subsequent reaction with carbonyl compounds gave the olefins(4) via the Peterson reaction.
