144434-08-2Relevant academic research and scientific papers
Recoverable Chiral Sulfoxides for Asymmetric Synthesis: Preparation, Regeneration and Application to the Asymmetric Aldol Reaction
Butlin, Roger J.,Linney, Ian D.,Critcher, Douglas J.,Mahon, Mary F.,Molloy, Kieran C.,Wills, Martin
, p. 1581 - 1590 (2007/10/02)
The synthesis of a novel source of chiral sulfoxide and its application to the control of asymmetric aldol reactions is described.The sulfoxide precursor S(S)R-(+)-cis-4 may be recycled and thus affords a considerable advantage over currently a
A New Class of Recoverable Chiral Sulphoxide: Application to the Asymmetric Synthesis of β-Hydroxy Esters.
Wills, Martin,Butlin, Roger J.,Linney, Ian D.
, p. 5427 - 5430 (2007/10/02)
Enantiomerically pure cyclic sulphinamide S(S)R-(+)-2 was prepared from homochiral sulphinic acid R-(-)-1 and subsequently converted to the ester S(S)R-(-)-3 via ring opening with an ester enolate.Aldol reactions of S(S)R-
