144442-95-5

Basic information

• Product Name: 1-Propanone, 2,3-dibromo-1-(4-fluorophenyl)-3-phenyl-
• CAS NO: 144442-95-5
• Molecular Formula: C15H11Br2FO
• Molecular Weight: 386.058
• Mol File: 144442-95-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1-Propanone, 2,3-dibromo-1-(4-fluorophenyl)-3-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Propanone, 2,3-dibromo-1-(4-fluorophenyl)-3-phenyl-(144442-95-5)
• EPA Substance Registry System: 1-Propanone, 2,3-dibromo-1-(4-fluorophenyl)-3-phenyl-(144442-95-5)

Safety Data

• Hazardous Substances Data: 144442-95-5(Hazardous Substances Data)

Usage

Classification

ketone

Physical state

clear, colorless to pale yellow liquid

Odor

strong, pungent

Usage

synthesis of various pharmaceuticals and organic compounds

Safety precautions

handle with caution and under proper safety measures

Laboratory use

reagent for organic synthesis, building block for creating complex chemical compounds

Upstream product

• 399-10-0 4'-fluorochalcone 
• 100-52-7 benzaldehyde 
• 22966-25-2 (E)-1-(4-fluorophenyl)-3-phenyl-2-propen-1-one 
• 403-42-9 1-(4-fluorophenyl)ethanone 

Downstream Products

• 37613-36-8 3-(4-fluorophenyl)-1,5-diphenyl-1H-pyrazole 

Relevant articles and documents

Modular access to 1,2-allenyl ketones based on a photoredox-catalysed radical-polar crossover process

Herein, a new protocol dealing with the preparation of 1,2-allenyl ketones has been successfully developedviathe reactions of enynes with radicals enabled by dual photoredox/copper catalysis. Based on the results of a deuteration experiment and the competition reaction between cyclopropanation and allenation, the mechanism based on a photoredox-neutral-catalysed radical-polar crossover process has been proposed. Synthetic applications of allenes have also been demonstrated.