144467-76-5

Upstream product

• 220474-68-0 2-iodobenzaldehyde-α-d₁ 
• 610-97-9 o-iodo-methyl-benzoic acid 
• 88-67-5 2-Iodobenzoic acid 
• 220474-66-8 α-deutero-2-iodobenzyl alcohol 

Downstream Products

• 108960-88-9 2-methyl-4-phenylisoquinolin-1(2H)-one 
• 220474-71-5 α,α-dideutero-2-iodo-N-methylbenzylamine 
• 220474-62-4 1,1-dideutero-4-hydroxy-2-methyl-4-phenyl-1,2,3,4-tetrahydroisoquinoline 
• 220474-74-8 α,α-dideutero-N-benzoylmethyl-2-iodo-N-methylbenzylamine 
• 1268358-37-7 C₂₃H₂₁⁽²⁾H₂NO₄ 
• 220474-68-0 2-iodobenzaldehyde-α-d₁ 
• 1610735-72-2 phenyl(2-((trimethylsilyl)ethynyl)phenyl)methan-d-ol 
• 1610735-63-1 d₁-1-ethynyl-2-(methoxy(phenyl)methyl)benzene 

Relevant academic research and scientific papers

CuSO4-Catalyzed Tandem C(sp3)-H Insertion Cyclization of Toluenes with Isonitriles to Form Indoles

A CuSO4-catalyzed tandem benzylic C-H insertion cyclization of toluene derivatives and isonitriles is described. The naturally abundant salt CuSO4 serves as a low-cost ligand-free redox catalyst. This reaction provides a practical mo

Divergent C-H Insertion-Cyclization Cascades of N-Allyl Ynamides

Gold carbene reactivity patterns were accessed by ynamide insertion into a C(sp3)-H bond. A substantial increase in molecular complexity occurred through the cascade polycyclization of N-allyl ynamides to form fused nitrogen-heterocycle scaffol

Pd(0)-catalyzed [1,5]-sigmatropic hydrogen shift of propargylic esters toward substituent naphthylamines

A novel and convenient carboannulation method for the synthesis of highly substituted naphthylamine derivatives has been developed though a Pd(0)-catalyzed [1,5]-sigmatropic hydrogen shift and cyclization reaction of propargyl esters.

New reduction reaction of benzylic alcohols with acid and proof of the intermolecular hydride shift mechanism

The new reduction reaction of the hydroxy groups of 4-hydroxy-4-phenyl- 1,2,3,4-tetrahydroisoquinolines (1) to the corresponding alkanes (2) with mineral and Lewis acids is reported. A stereoselective intermolecular hydride shift mechanism of the reduction was proved by reaction of the deuterated derivatives (14 and 15) of 1a with 10N HCl-C2H5OH and BBr3 in CH3CN.

Stereoselective intermolecular hydride shift mechanism of the new reduction of benzylic alcohols with acid

A stereoselective intermolecular hydride shift mechanism of the new reduction reaction of the benzylic hydroxy group of 4-hydroxy-4-phenyl-1,2,3,4-tetrahydroisoquinoline (1) to the corresponding alkane (2) with acid was proved by reaction of the deuterated derivatives (5 and 6) of 1.