Remote Asymmetric Induction Based on Carbonyl-Ene Reactions with Bishomoallylic Silyl Ether: Dramatic Changeover of Regioselectivity by the Remarkable Siloxy Effect

DOI: 10.1021/jo00049a011

Source and publish data:

Journal of Organic Chemistry p. 6105 - 6106 (1992)

Update date:2022-08-05

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Authors:

Shimizu, Masaki

Mikami, Koichi

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Article abstract of DOI:10.1021/jo00049a011

A new approach to remote asymmetric induction is described for not only a 1,4- but also a 1,5-relationship, which is based on the carbonyl-ene reactions with chiral bishomoallylic silyl ethers.Silyl ethers, rather than alkyl ethers, exhibit β-regiospecifi

Full text of DOI:10.1021/jo00049a011

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