Remote Asymmetric Induction Based on Carbonyl-Ene Reactions with Bishomoallylic Silyl Ether: Dramatic Changeover of Regioselectivity by the Remarkable Siloxy Effect

DOI: 10.1021/jo00049a011

Source and publish data:

Journal of Organic Chemistry p. 6105 - 6106 (1992)

Update date:2022-08-05

Topics:

Authors:

Shimizu, Masaki

Mikami, Koichi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00049a011

A new approach to remote asymmetric induction is described for not only a 1,4- but also a 1,5-relationship, which is based on the carbonyl-ene reactions with chiral bishomoallylic silyl ethers.Silyl ethers, rather than alkyl ethers, exhibit β-regiospecifi

Full text of DOI:10.1021/jo00049a011

Products guided by the article

Product name:6-Benzyloxy-2-hydroxy-3-vinyl-hexanoic acid methyl ester

Cas No:144693-97-0

R&D Labs maybe for 144693-97-0

Suzhou Chiral Pharmaceuticals Co., Ltd.

Contact:86-0512-63197058

Address:Building A, No. 2358, Chang'an Road, Wujiang Science Park
Hangzhou Chemfar Ltd.

Contact:+86-571-87859231, 87859237, 87859239

Address:1606,Huarong Times Mansion, No.3880 Jiangnan Avenue, Binjiang District, Hangzhou, China, 310053
AstaTech ( Chengdu) BioPharmaceutical Corp.

website:http://www.astabiochem.cn/

Contact:+86-15198215156-15198215156

Address:SICHUAN CHENGDU
jiangsu hualin chemical co.,ltd.

Contact:86-25-87787402

Address:jaingsu,china
SINO Industries Company Limited(expird)

Contact:86-29-85369724

Address:No.111, Jiefang Road, Xi’an, China

Relevant to this article

Molecular sieve mediated decarboxylative Mannich and aldol reactions of β-ketoacids

Doi:10.1016/j.tetlet.2013.06.030
(2013)
Preparation and palladium-mediated cross-coupling of α- benzoyloxyalkylzinc bromides

Doi:10.1016/j.tetlet.2013.05.114
(2013)
RAFT polymerization of s -vinyl sulfide derivatives and synthesis of block copolymers having two distinct optoelectronic functionalities

Doi:10.1021/ma400813e
(2013)
A highly selective and ratiometric fluorescent sensor for relay recognition of zinc(ii) and sulfide ions based on modulation of excited-state intramolecular proton transfer

Doi:10.1039/c3ra42931h
(2013)
2-aryl(hetaryl)-4H-[1,2,4]triazolo[1,5-a]benzimidazoles

Doi:10.1134/S107042801306016X
(2013)
The effect of the molecular structures of dicyanomethylene compounds on their supramolecular assembly, photophysical and electrochemical properties

Doi:10.1039/c3cp51957k
(2013)

Article Doi