144758-76-9Relevant academic research and scientific papers
Synthesis, structure and theoretical investigation into a homoleptic tris(dithiolene) tungsten
Arifin, Khuzaimah,Minggu, Lorna Jeffery,Daud, Wan Ramli Wan,Yamin, Bohari M.,Daik, Rusli,Kassim, Mohammad B.
, p. 208 - 215 (2014)
A new homoleptic dithiolene tungsten complex, tris-{1,2-bis(3,5- dimethoxyphenyl)-1,2-ethylenodithiolene-S,S′}tungsten, was successfully synthesized via a reaction of the thiophosphate ester and sodium tungstate. The thiophosphate ester was prepared from
Discotic nickel bis(dithiolene) complexes - Synthesis, optoelectrochemical and mesomorphic properties
Bui, Thanh-Tuan,Thiebaut, Olivier,Grelet, Eric,Achard, Marie-France,Garreau-De Bonneval, Benedicte,Moineau-Chane Ching, Kathleen I.
experimental part, p. 2663 - 2676 (2011/08/02)
Fifteen neutral long-chain-substituted discotic nickel bis(1,2-diphenyl-1, 2-ethenedithiolene) complexes [Ni(dpedt)2], including thirteen new compounds, have been synthesized by new short and efficient synthetic pathways. Physical investigations show that these complexes are thermally stable, possess good electron-accepting properties, and absorb light strongly in the near-infrared spectral region. Electrochemical and optical properties of [Ni(dpedt)2] depend moderately on the functionalities attached to the phenyl rings of the complexes. Their LUMO and HOMO energy levels are in the range -4.7 to -5.0 and -5.7 to -6.0 eV, respectively. Two octa(n-alkoxy)- substituted complexes exhibit a columnar liquid crystalline phase with hexagonal symmetry. These highly soluble complexes are potential candidates for use as electron-accepting and electron-transporting materials for active layers in organic electronic applications, such as field-effect transistors or photovoltaic devices. Electrochemical and optical studies as well as multiphase transition behavior are reported for a series of new nickel bis(dithiolene) complexes. The effects of the nature and position of the functional groupsattached to the periphery of the complexes are investigated. X-ray diffraction measurements regarding the hexagonal columnar mesophase are reported. Copyright
α,β-unsaturated aldehydes as substrates for asymmetric C-C bond forming reactions with thiamin diphosphate (ThDP)-dependent enzymes
Cosp, Anabel,Dresen, Carola,Pohl, Martina,Walter, Lydia,Roehr, Caroline,Mueller, Michael
experimental part, p. 759 - 771 (2009/04/10)
The enzymes benzaldehyde lyase (BAL) from Pseudomonas fluorescens, benzoylformate decarboxylase (BFD) from Pseudomonas putida and pyruvate decarboxylase (PDC) from Saccharomyces cerevisiae provide different C-C bond forming possibilities of α,β-unsaturated aldehydes with aliphatic and aromatic aldehydes. Structure elucidation and determination of the absolute configuration of the products, which were obtained with high regio- and stereoselectivity were carried out. Selective 1,2-reactivity with yields of 75% and >98% ee, for one single isomer (A) were obtained, by choosing the suitable enzyme in combination with the appropriate substrates. By varying enzymes or substrates the regioisomeric hydroxy ketones C, with up to >99% ee, can be obtained. The application of these new chiral building blocks in the synthesis of natural products or biological active substances is considerably facilitated by applying the different ThDP-dependent enzymes as catalysts.
Synthesis of an enantiopure fluorous 1,2-diphenyl-1,2-diaminoethane
Bayardon, Jerome,Sinou, Denis
, p. 425 - 428 (2007/10/03)
Enantiopure fluorous 1,2-diphenyl-1,2-ethanediamine bearing four fluorous ponytails and having 62.2% fluorine content has been prepared. Resolution of racemic 1,2-bis(3,5-dimethoxyphenyl)ethane-1,2-diamine with (-)-menthyl chloroformate followed by reduct
Reduction of 1,2-diketones with titanium tetraiodide: A simple approach to α-hydroxy ketones
Hayakawa,Sahara,Shimizu
, p. 7939 - 7942 (2007/10/03)
1,2-Diketones are readily reduced with titanium tetraiodide to give α-hydroxy ketones in good to excellent yields. Regioselectivity on the reduction of unsymmetrical substrates is also discussed. (C) 2000 Elsevier Science Ltd.
Photogeneration of amines from α-keto carbamates: Design and preparation of photoactive compounds
Cameron, James F.,Willson, C. Grant,Frechet, Jean M. J.
, p. 2429 - 2442 (2007/10/03)
The design and synthesis of substituted desyl (2-oxo-1,2-diphenylethyl) groups has been investigated to create new photolabile protecting groups. The photoreactivity of these chromophores stems from the diverse photochemistry of the desyl group. Several chromophore designs have been explored in which the substitution pattern of the parent desyl chromophore was varied systematically. The required benzoin chromophores are prepared by a variety of synthetic routes, depending on the structure of the benzoin chromophore desired. Symmetrical benzoins are readily available via the benzoin condensation. Unsymmetrical benzoins including 2,2-disubstituted α-hydroxy ketones are generally prepared via trimethylsilyl (TMS) masked cyanohydrins. On reaction with a Grignard reagent, the TMS masked cyanohydrin functions as an α-hydroxycarbonyl equivalent to form α-hydroxy ketones. Alternatively, lithiation of a TMS masked cyanohydrin generates a benzoyl anion equivalent which reacts with aldehydes and ketones to generate substituted benzoins. These desyl chromophores have significant potential as new photolabile protecting moieties for a variety of functional groups and are used to mask primary and secondary amines as photosensitive α-keto carbamates. The substituted benzoin carbamates are readily prepared from the appropriate benzoin by reaction with isocyanates or by activation as a mixed carbonate followed by reaction with the free amine. These α-keto carbamates are interesting for two main reasons. First, the facile synthesis of these materials indicates the ease of introduction of the desyl based photolabile group. Second, these α-keto carbamates may be used for rapid evaluation of novel photoactive desyl based chromophores.
