145103-19-1

Basic information

• Product Name: 2-(2-Benzoyl-1-cyan-1,2-dihydro-1-isochinolylmethyl)-benzoesaeureethylester
• Synonyms: 2-(2-Benzoyl-1-cyan-1,2-dihydro-1-isochinolylmethyl)-benzoesaeureethylester
• CAS NO: 145103-19-1
• Molecular Weight: 422.483
• Mol File: 145103-19-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-(2-Benzoyl-1-cyan-1,2-dihydro-1-isochinolylmethyl)-benzoesaeureethylester(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(2-Benzoyl-1-cyan-1,2-dihydro-1-isochinolylmethyl)-benzoesaeureethylester(145103-19-1)
• EPA Substance Registry System: 2-(2-Benzoyl-1-cyan-1,2-dihydro-1-isochinolylmethyl)-benzoesaeureethylester(145103-19-1)

Safety Data

• Hazardous Substances Data: 145103-19-1(Hazardous Substances Data)

Upstream product

• 87-24-1 ethyl 2-methylbenzoate 
• 844-25-7 2-benzoyl-1-cyano-1,2-dihydroisoquinoline 
• 7115-91-5 2-ethoxycarbonylbenzyl bromide 

Downstream Products

• 145313-93-5 8-Methyldibenzochinoliziniumchlorid*2H2O 

Relevant articles and documents

Synthesis of Dibenzoquinolizines - A New Entry to Protoberberines

A novel synthesis to prepare dibenzo-8-quinolizinones 8 is reported using the intramolecular cyclisation of the benzylated Reissert compounds 6 for the key step.Methylation of 8 by methyllithium gives partial deoxygenated coralynes 10 which in turn can be reduced by NaBH4 yielding the 8-methyltetrahydro-protoberberines 11.The structures are assigned by NMR-spectroscopy. Keywords.Reissert compounds; Intramolecular cyclisation; Dibenzo-8-quinolizinones; Deoxygenated coralynes; 8-Methyltetrahydro-protoberberines.