145212-81-3

Upstream product

• 6638-79-5 N,O-dimethylhydroxylamine*hydrochloride 
• 100-39-0 benzyl bromide 
• 93406-80-5 (S)-α-(N,N-dibenzylamino)propanoic acid 
• 111060-49-2 N,N-dibenzyl-L-alanine benzyl ester 

Downstream Products

• 80993-76-6 (S)-2-(Dibenzylamino)-1-phenyl-1-propanone 
• 216681-28-6 (S)-1-Cyclopent-1-enyl-2-dibenzylamino-propan-1-one 
• 216681-37-7 {(R)-2-[(S)-2-Benzylamino-prop-(Z)-ylidene]-cyclopentyl}-methanol 
• 216681-35-5 {(R)-2-[(S)-2-Dibenzylamino-prop-(Z)-ylidene]-cyclopentyl}-methanol 
• 216681-30-0 (1S,2S)-1-Cyclopent-1-enyl-2-dibenzylamino-propan-1-ol 
• 216681-39-9 Benzyl-{(S)-2-[(R)-2-hydroxymethyl-cyclopent-(Z)-ylidene]-1-methyl-ethyl}-carbamic acid tert-butyl ester 
• 216681-41-3 (R)-2-[(S)-2-(Benzyl-tert-butoxycarbonyl-amino)-prop-(Z)-ylidene]-cyclopentanecarboxylic acid 
• 1350712-56-9 (2S,3S)-3-dibenzylamino-1,1,1-trifluoro-2-methyl-butan-2-ol 
• 912538-45-5 (2S,3S)-3-(N,N-dibenzylamino)-1-(4-methoxyphenyl)butan-2-ol 
• 912538-52-4 (2S,3S)-N,N-dibenzyl-3-methoxy-4-(4-methoxyphenyl)-2-butanamine 
• 912538-44-4 (3S)-3-(N,N-dibenzylamino)-1-(4-methoxyphenyl)butan-2-one 
• 145147-72-4 (2S,4R)-2-(Dibenzylamino)-4-phenyl-3-pentanone 
• 145147-72-4 (2S,4S)-2-(Dibenzylamino)-4-phenyl-3-pentanone 

Relevant academic research and scientific papers

Synthesis of enantiopure cis-decahydroquinolines from homotyramines by Birch reduction and aminocyclization

Birch reduction of homotyramines with a syn-β-amino alcohol unit followed by acid treatment of formed dihydroanisole derivatives gives polysubstituted enantiopure cis-decahydroquinolines. The stereoselectivity of the process differs if the hydroxyl group

On the Configurational Stability of α-Methylbenzyllithium

α-Methylbenzyllithium (6) should possess either central or planar chirality.The rate of enantiomerization of 6 at -78 deg C was found to be faster than its addition to the amide 7, the ketone 8, or to the aldegyde 10, according to a test based on kinetic