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phenyl 3-(4-methoxyphenyl)propiolate is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 1452154-65-2 Structure
  • Basic information

    1. Product Name: phenyl 3-(4-methoxyphenyl)propiolate
    2. Synonyms: phenyl 3-(4-methoxyphenyl)propiolate
    3. CAS NO:1452154-65-2
    4. Molecular Formula:
    5. Molecular Weight: 252.269
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 1452154-65-2.mol
  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: phenyl 3-(4-methoxyphenyl)propiolate(CAS DataBase Reference)
    10. NIST Chemistry Reference: phenyl 3-(4-methoxyphenyl)propiolate(1452154-65-2)
    11. EPA Substance Registry System: phenyl 3-(4-methoxyphenyl)propiolate(1452154-65-2)
  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 1452154-65-2(Hazardous Substances Data)

1452154-65-2 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 1452154-65-2 includes 10 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 7 digits, 1,4,5,2,1,5 and 4 respectively; the second part has 2 digits, 6 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 1452154-65:
(9*1)+(8*4)+(7*5)+(6*2)+(5*1)+(4*5)+(3*4)+(2*6)+(1*5)=142
142 % 10 = 2
So 1452154-65-2 is a valid CAS Registry Number.

1452154-65-2Relevant articles and documents

Synthesis of 3-Sulfenylated Coumarins: BF3·Et2O-Mediated Electrophilic Cyclization of Aryl Alkynoates Using N-Sulfanylsuccinimides

Gao, Wen-Chao,Liu, Tao,Zhang, Bing,Li, Xing,Wei, Wen-Long,Liu, Qiang,Tian, Jun,Chang, Hong-Hong

, p. 11297 - 11304 (2016)

A simple and efficient metal-free sulfenylation/cyclization of aryl alkynoates has been developed, obtaining various 3-sulfenylated coumarins in moderate to excellent yields. In the presence of BF3·Et2O, the stable and readily access

Chlorinative Cyclization of Aryl Alkynoates Using NCS and 9-Mesityl-10-methylacridinium Perchlorate Photocatalyst

Pramanik, Milan,Mathuri, Ashis,Sau, Sudip,Das, Monojit,Mal, Prasenjit

supporting information, p. 8088 - 8092 (2021/10/12)

In a chlorinative cyclization, Mes-Acr-MeClO4 acted as a visible-light photocatalyst to obtain 3-chlorocoumarins from aryl alkynoates and N-chlorosuccinimide (NCS). The radical initiated reaction proceeded in a cascading manner via Cl- addition to alkynoa

Atom Transfer Oxidative Radical Cascade of Aryl Alkynoates towards 1,1-Dichalcogenide Olefins

Sahoo, Harekrishna,Ramakrishna, Isai,Mandal, Anup,Baidya, Mahiuddin

, p. 4549 - 4552 (2019/07/31)

An oxidative trifunctionalization of aryl alkynoates has been devised via the chalcogenide radical triggered intramolecular 1,4-aryl migration/decarboxylation cascade to prepare 1,1-dichalcogenide tetrasubstituted alkenes in high yields (up to 98 %). This operationally simple reaction proceeds under metal-free conditions, can be executed on gram scale, and highlights formal 1,1-difunctionalization of alkynes. Synthetic potential of this protocol was demonstrated through a twofold cascade rearrangement to access highly conjugated tetra-selenylated alkenes along with a cross-dehydrogenative annulation to prepare fluorene derivative.

Visible-light photoredox catalyzed cyclization of aryl alkynoates for the synthesis of trifluoromethylated coumarins

Bu, Mei-jie,Lu, Guo-ping,Cai, Chun

, p. 70 - 74 (2018/07/13)

A strategy for the synthesis of coumarin derivatives via visible-light photoredox catalysis has been developed using fac-Ir(ppy)3 as the photocatalyst under mild conditions. Trifluoromethanesulfonyl chloride is utilized as the trifluoromethylat

Tandem trifluoromethylthiolation/aryl migration of aryl alkynoates to trifluoromethylthiolated alkenes

Li, Huan,Liu, Shuai,Huang, Yangen,Xu, Xiu-Hua,Qing, Feng-Ling

, p. 10136 - 10139 (2017/09/23)

A trifluoromethylthiolation initiated aryl migration of aryl alkynoates was disclosed. This protocol employs AgSCF3 as the SCF3 source and MeCN as both the solvent and the hydrogen source. This provides a new access to trifluoromethylthiolated alkenes from readily available substrates and reagents.

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