145236-11-9Relevant academic research and scientific papers
A simple route to acylsilane enol esters from enol esters
Wright, Stephen W.
, p. 1841 - 1842 (1994)
A new methodology is described for the synthesis of enol esters of acylsilanes, from readily available vinyl esters. A solution of LDA is added to a mixture of an enol ester (preferably sterically congested, with only one α- carboxyl proton, eg 2-ethylhexanoate) and a chlorosilane at -78°C to afford the product.
Synthesis of acylsilanes via transmetalation of 1-triorganosilyloxyvinyltin derivatives
Verlhac, Jean-Baptiste,Kwon, HeeAn,Pereyre, Michel
, p. C13 - C18 (2007/10/02)
Transmetalation of 1-triorganosilyloxyvinyltin derivatives occurs with a reverse Brook rearrangement.Subsequent trapping with various electrophiles affords new acylsilanes.
